2-(2-formylvinyl)-5,10,15,20-tetraphenylporphyrinatocopper | 940948-89-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: 2-(2-formylvinyl)-5,10,15,20-tetraphenylporphyrinatocopper
• CAS: 940948-89-0
• 化学式: C₄₇H₃₀CuN₄O
• 分子量: 730.327
• InChiKey: QGFLKGSAQDZEKN-GBGVRRJWSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  2-(2-formylvinyl)-5,10,15,20-tetraphenylporphyrinatocopper 在 甲酸 、 5% Pd(II)/C(eggshell) 作用下， 以 1,4-二氧六环 为溶剂， 反应 3.0h， 以77%的产率得到2-propyl-5,10,15,20-tetraphenylporphyrinatocopper
  参考文献：
  名称：

  Porphyrins and their derivatives: XXVI. Synthesis and properties of 2-(3-butenyl)-5,10,15,20-tetraphenylporphyrin

  摘要：

  2-[2-(1,3-Dioxolan-2-yl)vinyl]-5,10,15,20-tetraphenylporphyrin and its copper complex were reduced into the corresponding ethyldioxolanes by diimide generated in the system hydrazine hydrate - air oxygen - pyridine. The hydrolysis of the obtained ethyldioxolanes results in the formylethyl derivatives that react with the methylenetriphenylphosphorane to form 2-(3-butenyl)-5,10,15,20-tetraphenyl porphyrin and its copper complex.

  DOI：

  10.1134/s1070428010090241
• 作为产物：
  描述：

  2-[2-(1,3-dioxolan-2-yl)vinyl]-5,10,15,20-tetraphenylporphyrinatocopper 在 碘酸 作用下， 以 水 、 苯 为溶剂， 反应 1.5h， 以75%的产率得到2-(2-formylvinyl)-5,10,15,20-tetraphenylporphyrinatocopper
  参考文献：
  名称：

  Porphyrins and their derivatives: XXVI. Synthesis and properties of 2-(3-butenyl)-5,10,15,20-tetraphenylporphyrin

  摘要：

  2-[2-(1,3-Dioxolan-2-yl)vinyl]-5,10,15,20-tetraphenylporphyrin and its copper complex were reduced into the corresponding ethyldioxolanes by diimide generated in the system hydrazine hydrate - air oxygen - pyridine. The hydrolysis of the obtained ethyldioxolanes results in the formylethyl derivatives that react with the methylenetriphenylphosphorane to form 2-(3-butenyl)-5,10,15,20-tetraphenyl porphyrin and its copper complex.

  DOI：

  10.1134/s1070428010090241

文献信息

• Porphins and their derivatives: XXIV. meso-Tetraphenylporphyrins with β-pyrazole rings
  作者：Yu. V. Ishkov、Z. I. Zhilina、A. V. Mazepa、S. V. Vodzinskii、L. P. Bardai

  DOI：10.1134/s1070428006080021

  日期：2006.8

  A series of 5-substituted 2-(2-phenyl-3,4-dihydro-2H-pyrazol-3-yl)porphyrins was prepared by treating with phenylhydrazine tetraphenylporphyrin derivatives containing in the beta-position fragments of beta-unsaturated ketones or aldehydes. The compounds obtained were oxidized. with o-chloranil into the corresponding pyrazolylporphyrins.