8,9-dimethyl-2,3,5,6-tetrahydro-4H-1-oxa-3a-azaphenalene | 1338594-81-2

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: 8,9-dimethyl-2,3,5,6-tetrahydro-4H-1-oxa-3a-azaphenalene
• 英文别名: 7,8-Dimethyl-4-oxa-1-azatricyclo[7.3.1.05,13]trideca-5(13),6,8-triene
• CAS: 1338594-81-2
• 化学式: C₁₃H₁₇NO
• 分子量: 203.284
• InChiKey: MHKYUTUYRSMKEW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  7,8-Dimethyl-4-oxa-1-azatricyclo[7.3.1.05,13]trideca-5(13),6,8-trien-10-one 在 palladium 10% on activated carbon 、 氢气 作用下， 以 乙醇 为溶剂， 生成 8,9-dimethyl-2,3,5,6-tetrahydro-4H-1-oxa-3a-azaphenalene
  参考文献：
  名称：

  2,3-二氢-6H-1-氧杂-3a-氮杂-苯并萘及其苯并/杂融合类似物的合成

  摘要：

  一种用于高度取代的苯并和2，3-二氢-6-的杂稠合类似物合成简单和有效的方法ħ氧杂基-3a-氮杂-非那烯，用2开发ħ -1，4-苯并恶嗪和α-oxoketene二硫代乙缩醛。J.杂环化​​学。（2011）。

  DOI：

  10.1002/jhet.680

文献信息

• Azo-metal chelate dye and optical recording medium
  申请人：Satake Kenichi

  公开号：US20070054219A1

  公开（公告）日：2007-03-08

  The azo-metal chelate dye of the present invention is formed, for example, from zinc (divalent) as a center metal ion and an azo compound bonded with a coupler component having an amino group and a fluorine-substituted alkylsulfonylamino group subjected to condensed ring-formation to have a 1,3,4-thiazole ring as a diazo component.
• Optical recording material and optical recording medium
  申请人：Miyazawa Takashi

  公开号：US20070184386A1

  公开（公告）日：2007-08-09

  The present invention provides a high level optical recording material which is capable of recording and reading by a blue laser with a short wavelength. An optical recording material comprises an organic dye compound A whose absorption maximum wavelength (λmax) is not less than 340 nm and not more than 440 nm and a metal-complex compound B whose absorption maximum wavelength (λmax) is not less than 500 nm and not more than 900 nm, the content of the organic dye compound A is higher than the content of the metal-complex compound B, and light resistance x determined by a predetermined method is not less than 30%.
• US7507524B2
  申请人：——

  公开号：US7507524B2

  公开（公告）日：2009-03-24