2-(3-(2,1,3-benzoxadiazol-4-yl)phenyl)-9-(1-hexylheptyl)anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone | 1417610-41-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 2-(3-(2,1,3-benzoxadiazol-4-yl)phenyl)-9-(1-hexylheptyl)anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone
• 英文别名: 7-[3-(2,1,3-Benzoxadiazol-4-yl)phenyl]-18-tridecan-7-yl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone；7-[3-(2,1,3-benzoxadiazol-4-yl)phenyl]-18-tridecan-7-yl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone
• CAS: 1417610-41-3
• 化学式: C₄₉H₄₂N₄O₅
• 分子量: 766.896
• InChiKey: URHPPUNGHKQIAE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12
• 重原子数：
  58
• 可旋转键数：
  13
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  114
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  3-(2,1,3-benzoxadiazol-4-yl)aniline 、 N-(1-hexylheptyl)-perylene-3,4,9,10-tetracarboxylic-3,4-carboximide-9,10-anhydride 在 喹啉 、 zinc diacetate 作用下， 反应 5.0h， 以80%的产率得到2-(3-(2,1,3-benzoxadiazol-4-yl)phenyl)-9-(1-hexylheptyl)anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone
  参考文献：
  名称：

  Benzothiadiazoloperylenes and Benzoxadiazoloperylenes: Amorphous Functional Materials

  摘要：

  2,1,3-Benzothiadiazole or 2,1,3-benzoxadiazole were magnesiated (TMP2Mg center dot 2LiCl) and efficiently attached to perylene and benzoperylene building blocks providing amorphous light-absorbing materials where FRET energy transfer proceeds between the 2,1,3-benzothiadiazole or 2,1,3-benzoxadiazole and the perylene units. Some of these new materials were obtained as amorphous solids of interest for material science.

  DOI：

  10.1055/s-0032-1316785

文献信息

• Benzothiadiazoloperylenes and Benzoxadiazoloperylenes: Amorphous Functional Materials
  作者：Heinz Langhals、Paul Knochel、Andreas Walter、Silvia Zimdars

  DOI：10.1055/s-0032-1316785

  日期：——

  2,1,3-Benzothiadiazole or 2,1,3-benzoxadiazole were magnesiated (TMP2Mg center dot 2LiCl) and efficiently attached to perylene and benzoperylene building blocks providing amorphous light-absorbing materials where FRET energy transfer proceeds between the 2,1,3-benzothiadiazole or 2,1,3-benzoxadiazole and the perylene units. Some of these new materials were obtained as amorphous solids of interest for material science.