[Ni(2-aminomethylpyridine)2(tricyanomethanide)2] | 875927-35-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [Ni(2-aminomethylpyridine)2(tricyanomethanide)2]
• CAS: 875927-35-8
• 化学式: C₂₀H₁₆N₁₀Ni
• 分子量: 455.104
• InChiKey: HZBQCKYUTGJBHZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  trans-[Ni(2-aminomethylpyridine)2](NO3)2 、 三氰基甲烷化钾 以 水 为溶剂， 以23%的产率得到[Ni(2-aminomethylpyridine)2(tricyanomethanide)2]
  参考文献：
  名称：

  Synthesis, structures and magnetic properties of 2-aminomethylpyridine–Ni(II) complexes

  摘要：

  A family of complexes of Ni(II), 2-aminomethylpyridine (ampy) and tricyanomethanide (tcm) have been prepared and studied by IR, X-ray crystallography and variable temperature susceptibility. The complexes synthesized include [Ni(ampy)(3)](ClO4)(2) (1), [Ni(ampy)(3)](tcm)(PF6) (2), [Ni(ampy)(3)](PF6)(2) (3), [Ni(ampy)(2)(H2O)(2)]Cl-2 (4), and [Ni(ampy)(2)(tcm)(2)] (5). No coordination polymers of tcm were obtained. The magnetic behavior of the complexes, and the known material [Ni(ampy)(NO3)(2)], is dominated by single-ion anisotropy effects with D-values in the range of -2 to -12 K, although some compounds show a weak antiferromagnetic interaction. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.07.039