1,1-difluoro-2-(non-1-en-2-yl)cyclopropane | 944943-38-8

• 分子结构分类: 有机化合物 - 有机卤素化合物
• 英文名称: 1,1-difluoro-2-(non-1-en-2-yl)cyclopropane
• CAS: 944943-38-8
• 化学式: C₁₂H₂₀F₂
• 分子量: 202.288
• InChiKey: FGOFATDDBFEEPD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.56
• 重原子数：
  14.0
• 可旋转键数：
  7.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  3-methylenedec-1-ene 、 二溴二氟甲烷 在 三甲基氯硅烷 、 碘 、 锌 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 以18.8%的产率得到1,1-difluoro-2-heptyl-2-vinylcyclopropane
  参考文献：
  名称：

  Synthesis and radical ring opening behaviour of 1,1-difluoro-2-heptyl-2-vinylcyclopropane and some of its isomers

  摘要：

  The syntheses and characterisations of 1,1-difluoro-2-heptyl-2-vinylcyclopropane and some of its isomers are described together with attempts to effect free radical ring opening polymerisation. We have recently shown that the parent monomer, 1,1-difluoro-2-vinylcyclopropane, undergoes predominantly 1,4-addition ring opening in contrast to the more usual 1,5-ring opening of other substituted vinylcyclopropanes and we find that the same anomalous behaviour occurs in this work confirming the influence of fluorine on the course of cyclopropane ring opening proposed by Dolbier. The presence of an alkyl chain modifies the ratios of 1,4- to 1,5-ring opening compared to that found in the unsubstituted parent monomer. In addition an the unexpected behaviour of different alkyl substituted buta-1,3-dienes towards difluorocarbene addition is described. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2006.07.008