zinc 5-(4-(4’-phenyl-(1-H-1,2,3-triazol-1’-yl))phenyl)-10,15,20-tris-(2,3,4,5,6-pentafluorophenyl)porphyrin | 1474046-11-1

• 分子结构分类: 有机化合物
• 英文名称: zinc 5-(4-(4’-phenyl-(1-H-1,2,3-triazol-1’-yl))phenyl)-10,15,20-tris-(2,3,4,5,6-pentafluorophenyl)porphyrin
• CAS: 1474046-11-1
• 化学式: C₅₂H₁₈F₁₅N₇Zn
• 分子量: 1091.13
• InChiKey: NCVZDZIDVSHLBA-JUJBFAPESA-N

反应信息

• 作为反应物：
  描述：

  zinc 5-(4-(4’-phenyl-(1-H-1,2,3-triazol-1’-yl))phenyl)-10,15,20-tris-(2,3,4,5,6-pentafluorophenyl)porphyrin 在 盐酸 作用下， 以 1,4-二氧六环 、 二氯甲烷 为溶剂， 反应 0.08h， 以86%的产率得到5-(4-(4’-phenyl-(1-H-1,2,3-triazol-1’-yl))phenyl)-10,15,20-tris-(2,3,4,5,6-pentafluorophenyl)porphyrin
  参考文献：
  名称：

  A Mild, Facile, One-Pot Synthesis of Zinc Azido Porphyrins as Substrates for Use in Click Chemistry

  摘要：

  The conversion of porphyrins bearing primary amines into zinc-protected azido porphyrins utilising a diazo-transfer reagent is reported. This method allows the mild, facile, and one-pot synthesis of zinc azido porphyrins bearing a range of meso functionalities, producing the required porphyrin in high yield. Reactivity of the azide functionality is demonstrated by subsequent model click reactions to produce triazole derivatives.

  DOI：

  10.1055/s-0033-1339694
• 作为产物：
  描述：

  5-[4-aminophenyl]-10,15,20-tri-(2,3,4,5,6-pentafluorophenyl)porphyrin 在 copper(ll) sulfate pentahydrate 、 3-azidosulfonyl-3H-imidazole-1-ium hydrogen sulfate 、 sodium ascorbate 、 三乙胺 作用下， 以 四氢呋喃 、 甲醇 、 二氯甲烷 、 水 为溶剂， 反应 22.0h， 生成 zinc 5-(4-(4’-phenyl-(1-H-1,2,3-triazol-1’-yl))phenyl)-10,15,20-tris-(2,3,4,5,6-pentafluorophenyl)porphyrin
  参考文献：
  名称：

  A Mild, Facile, One-Pot Synthesis of Zinc Azido Porphyrins as Substrates for Use in Click Chemistry

  摘要：

  The conversion of porphyrins bearing primary amines into zinc-protected azido porphyrins utilising a diazo-transfer reagent is reported. This method allows the mild, facile, and one-pot synthesis of zinc azido porphyrins bearing a range of meso functionalities, producing the required porphyrin in high yield. Reactivity of the azide functionality is demonstrated by subsequent model click reactions to produce triazole derivatives.

  DOI：

  10.1055/s-0033-1339694