1,8-bis(2-hydroxyphenyl)naphthalene | 1531595-92-2

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 1,8-bis(2-hydroxyphenyl)naphthalene
• 英文别名: 1,8-bis(2-phenol)naphthalene；2-[8-(2-Hydroxyphenyl)naphthalen-1-yl]phenol；2-[8-(2-hydroxyphenyl)naphthalen-1-yl]phenol
• CAS: 1531595-92-2
• 化学式: C₂₂H₁₆O₂
• 分子量: 312.368
• InChiKey: BEKYSJWCPFFMBZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  24
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,8-bis(2-methoxyphenyl)naphthalene 在 三溴化硼 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 以77%的产率得到1,8-bis(2-hydroxyphenyl)naphthalene
  参考文献：
  名称：

  ortho-Substituted 1,8-Diarylnaphthalenes: Conformational Thermodynamics and Kinetics

  摘要：

  1,8-Diarylnaphthalenes show interesting potential as chiral sensors, environment sensors and stereodynamic switches. The kinetics and thermodynamics of the conformational equilibria of two such compounds are described. These compounds, along with others reported previously, show that several features can be used to tune the conformational behaviour of these compounds, giving the possibility to design molecules for specific applications in the future.

  DOI：

  10.1055/s-0033-1339695

文献信息

• ortho-Substituted 1,8-Diarylnaphthalenes: Conformational Thermodynamics and Kinetics
  作者：Matthew Fuchter、Dilraj Judge、Peter Haycock、Robert Richardson

  DOI：10.1055/s-0033-1339695

  日期：——

  1,8-Diarylnaphthalenes show interesting potential as chiral sensors, environment sensors and stereodynamic switches. The kinetics and thermodynamics of the conformational equilibria of two such compounds are described. These compounds, along with others reported previously, show that several features can be used to tune the conformational behaviour of these compounds, giving the possibility to design molecules for specific applications in the future.