| 194223-34-2

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• CAS: 194223-34-2
• 化学式: C₈H₁₈N₄O₆Rh*ClO₄
• 分子量: 468.61
• InChiKey: RMIWJHVFCDOPSA-RZHIZDBDSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 三乙基膦 以 乙醇 、 水 为溶剂， 生成
  参考文献：
  名称：

  Cationic rhodium(III) bisdimethylglyoximates with water and triphenylphosphine axial ligands

  摘要：

  Preparations of [Rh(Hdmg)(2)(H2O)(2)]ClO4 (1) (Hdmg=dimethylgyoximate) from [Rh(H2O)(6)](ClO4)(3) and dimethylglyoxime and of [Rh(Hdmg)(2)(PPh3)(2)]ClO4 (2) from 1 and PPh3 are described. 1 crystallizes in the C2/c space group with a=14.910(3), b=6.058(1), c=18.617(4) Angstrom, beta=107.649(8)degrees Z=4. The structure was refined up to R=0.021 for 1849 reflections. The IR and NMR spectra and electrochemical behavior of 1 and 2 are discussed and compared with other rhodoximes. Three polarographic and CV processes can be detected for 2, the first two, respectively to Rh(Il) and Rh(I), being followed by fast reactions.

  DOI：

  10.1016/s0020-1693(97)05461-3
• 作为产物：
  描述：

  hexaaquarhodium(III) perchlorate 、 二甲基乙二醛肟 在 KOH 作用下， 以 乙醇 、 水 为溶剂， 以30%的产率得到
  参考文献：
  名称：

  Cationic rhodium(III) bisdimethylglyoximates with water and triphenylphosphine axial ligands

  摘要：

  Preparations of [Rh(Hdmg)(2)(H2O)(2)]ClO4 (1) (Hdmg=dimethylgyoximate) from [Rh(H2O)(6)](ClO4)(3) and dimethylglyoxime and of [Rh(Hdmg)(2)(PPh3)(2)]ClO4 (2) from 1 and PPh3 are described. 1 crystallizes in the C2/c space group with a=14.910(3), b=6.058(1), c=18.617(4) Angstrom, beta=107.649(8)degrees Z=4. The structure was refined up to R=0.021 for 1849 reflections. The IR and NMR spectra and electrochemical behavior of 1 and 2 are discussed and compared with other rhodoximes. Three polarographic and CV processes can be detected for 2, the first two, respectively to Rh(Il) and Rh(I), being followed by fast reactions.

  DOI：

  10.1016/s0020-1693(97)05461-3