(6-Prop-2-enoyloxy-3-pentacyclo[6.6.6.02,7.09,14.015,20]icosa-2,4,6,9,11,13,15,17,19-nonaenyl) prop-2-enoate | 1219971-50-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: (6-Prop-2-enoyloxy-3-pentacyclo[6.6.6.02,7.09,14.015,20]icosa-2,4,6,9,11,13,15,17,19-nonaenyl) prop-2-enoate
• 英文别名: (6-prop-2-enoyloxy-3-pentacyclo[6.6.6.02,7.09,14.015,20]icosa-2,4,6,9,11,13,15,17,19-nonaenyl) prop-2-enoate
• CAS: 1219971-50-2
• 化学式: C₂₆H₁₈O₄
• 分子量: 394.427
• InChiKey: PBBDVRMFDLQSOP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  30
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  triptycene-1,4-diol 、 丙烯酰氯 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 以70%的产率得到(6-Prop-2-enoyloxy-3-pentacyclo[6.6.6.02,7.09,14.015,20]icosa-2,4,6,9,11,13,15,17,19-nonaenyl) prop-2-enoate
  参考文献：
  名称：

  Synthesis and characterization of triptycene type cross-linker and its use in photoinduced curing applications

  摘要：

  A novel triptycene type diacrylate cross-linker, triptycene hydroquinone diacrylate (THDA) was synthesized from the reaction of triptycene hydroquinone with acryloyl chloride and characterized. The photocuring behaviour and the reaction kinetics of the synthesized cross-linker were investigated by means of photo-differential scanning calorimetry (photo-DSC) experiments. Formulations containing monofunctional (meth)acrylate monomers, namely glycidyl methacrylate (GMA), 2-hydroxyethyl acrylate (HEA), 2-hydroxyethyl methacrylate (HEMA), and 2-ethylhexyl methacrylate (EHMA), crosslinker, THDA and 2,2-dimethoxy-2-phenylacetophenone (DMPA) as a photoinitiator were irradiated. A conventional cross-linker without triptycene unit Such as hydroquinone diacrylate (HDA) was used under the same conditions for comparison. The effects of the Structure of the monofunctional monomer and triptycene moiety on the photopolymerization kinetics were evaluated and discussed. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2010.01.005

文献信息

• Synthesis and characterization of triptycene type cross-linker and its use in photoinduced curing applications
  作者：Sahin Ates、Binnur Aydogan、Lokman Torun、Yusuf Yagci

  DOI：10.1016/j.polymer.2010.01.005

  日期：2010.2

  A novel triptycene type diacrylate cross-linker, triptycene hydroquinone diacrylate (THDA) was synthesized from the reaction of triptycene hydroquinone with acryloyl chloride and characterized. The photocuring behaviour and the reaction kinetics of the synthesized cross-linker were investigated by means of photo-differential scanning calorimetry (photo-DSC) experiments. Formulations containing monofunctional (meth)acrylate monomers, namely glycidyl methacrylate (GMA), 2-hydroxyethyl acrylate (HEA), 2-hydroxyethyl methacrylate (HEMA), and 2-ethylhexyl methacrylate (EHMA), crosslinker, THDA and 2,2-dimethoxy-2-phenylacetophenone (DMPA) as a photoinitiator were irradiated. A conventional cross-linker without triptycene unit Such as hydroquinone diacrylate (HDA) was used under the same conditions for comparison. The effects of the Structure of the monofunctional monomer and triptycene moiety on the photopolymerization kinetics were evaluated and discussed. (C) 2010 Elsevier Ltd. All rights reserved.