2,6-bis(3,4,5-tridodecyloxybenzoylamino)-4-iodo-toluene | 798567-78-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,6-bis(3,4,5-tridodecyloxybenzoylamino)-4-iodo-toluene
• 英文别名: 3,4,5-tridodecoxy-N-[5-iodo-2-methyl-3-[(3,4,5-tridodecoxybenzoyl)amino]phenyl]benzamide
• CAS: 798567-78-9
• 化学式: C₉₃H₁₆₁IN₂O₈
• 分子量: 1562.21
• InChiKey: PHPZSBYNSQYWGT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  37.9
• 重原子数：
  104
• 可旋转键数：
  76
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  114
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  5-乙炔基-2-吡啶-2-基吡啶 、 2,6-bis(3,4,5-tridodecyloxybenzoylamino)-4-iodo-toluene 在 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 、 二异丙胺 作用下， 以 四氢呋喃 为溶剂， 以63%的产率得到5-[2,6-bis(3,4,5-tridodecyloxybenzoylamino)-4-ethynyl-toluene]-2,2'-bipyridine
  参考文献：
  名称：

  New Platforms Integrating Ethynyl-Grafted Modules for Organogels and Mesomorphic Superstructures

  摘要：

  A methyldiacylaminophenyl core substituted with gallic derivatives and alkynyl functions has been synthesized from 2,6-diamino-4-iodotoluene. By heating the iodo and ethynyl molecules, typical columnar mesophases are observed and the C-12 synthons bearing a protected terminal alkyne group gelified acetone, via the formation of interlocked fibers which are promoted by intermolecular hydrogen bonding.

  DOI：

  10.1021/ol048503n
• 作为产物：
  描述：

  3,4,5-tris(dodecanyloxy)benzoyl chloride 、 2,6-diamino-4-iodo-toluene 在 sodium carbonate 作用下， 以 丙酮 为溶剂， 反应 20.0h， 以86%的产率得到2,6-bis(3,4,5-tridodecyloxybenzoylamino)-4-iodo-toluene
  参考文献：
  名称：

  New Platforms Integrating Ethynyl-Grafted Modules for Organogels and Mesomorphic Superstructures

  摘要：

  A methyldiacylaminophenyl core substituted with gallic derivatives and alkynyl functions has been synthesized from 2,6-diamino-4-iodotoluene. By heating the iodo and ethynyl molecules, typical columnar mesophases are observed and the C-12 synthons bearing a protected terminal alkyne group gelified acetone, via the formation of interlocked fibers which are promoted by intermolecular hydrogen bonding.

  DOI：

  10.1021/ol048503n

文献信息

• Tuning the Thermotropic and Lyotropic Properties of Liquid-Crystalline Terpyridine Ligands
  作者：Franck Camerel、Bertrand Donnio、Cyril Bourgogne、Marc Schmutz、Daniel Guillon、Patrick Davidson、Raymond Ziessel

  DOI：10.1002/chem.200501431

  日期：2006.5.24

  A rational synthetic strategy is developed to provide compact and simple terpyridine (terpy) mesogens that show liquid-crystallinity both as pure compounds and in organic solution (amphotropic compound). The use of a central 4-methyl-3,5-diacylaminophenyl platform equipped with two lateral aromatic rings, each bearing three appended aliphatic chains, allows connection of a 2,2':6',2''-terpyridine fragment

  已开发出一种合理的合成策略，以提供紧凑且简单的三联吡啶（三联吡啶）介晶，该三联吡啶在纯化合物和有机溶液（两性化合物）中均显示液晶性。使用带有两个侧面芳香环的中心4-甲基-3,5-二酰基氨基苯基平台，每个芳香环带有三个附加的脂族链，可以通过极性连接2,2'：6'，2''-吡啶吡啶片段基团，例如酯，酰胺或平面共轭炔烃连接基。对于T（12）ester和T（12）amide支架，最好将中间相描述为层状相，其中分子自组装成层状保持在一起的柱状叠层。在T（12）酰胺的情况下，额外的酰胺键会导致层状相的显着稳定。出现柱状有序的驱动力是酰胺基团的氢键相互作用，这会引起三联亚基从头到尾的π堆积。如T（12）乙炔基化合物中所述，通过非极化但线性的炔烃间隔基取代极性连接基，可提供以p2gg对称的矩形晶格组织的柱状中间相。在这种布置中，通过氢键键合和pi-pi堆积以头对尾的方式堆积成二聚体的两个非粘性分子以形成列
• Ionic Self-Assembly Provides Dense Arrays of Individualized, Aligned Single-Walled Carbon Nanotubes
  作者：Jean-Hubert Olivier、Pravas Deria、Jaehong Park、Amar Kumbhar、Maria Andrian-Albescu、Michael J. Therien

  DOI：10.1002/anie.201307256

  日期：2013.12.2

  Wrap and stack: Polyanionic [arylene]ethynylene polymers that helically wrap single‐walled carbon nanotubes (SWNTs) enable the production of functionalized SWNTs that are soluble in organic solvents. These SWNTs can assemble into structures featuring aligned nanotubes that maintain the optoelectronic properties of individual SWNTs.

  包装和堆叠：螺旋缠绕单壁碳纳米管（SWNT）的聚阴离子[亚芳基]乙炔聚合物可生产可溶于有机溶剂的功能化SWNT。这些单壁碳纳米管可以组装成具有排列的纳米管的结构，这些纳米管可以保持单个单壁碳纳米管的光电性能。