4-(3-丁烯-1-基氧基)苯胺 | 667465-97-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: 4-(3-丁烯-1-基氧基)苯胺
• 英文名称: 1-(4-aminophenoxy)-3-butene
• 英文别名: p-(but-3-enyloxy)aniline；4-(3-Buten-1-yloxy)aniline；4-but-3-enoxyaniline
• CAS: 667465-97-6
• 化学式: C₁₀H₁₃NO
• 分子量: 163.219
• InChiKey: OZSCDMXYGLIPBH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  35.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  氯甲酸-9-芴基甲酯 、 4-(3-丁烯-1-基氧基)苯胺 在 N,N-二异丙基乙胺 作用下， 以 1,4-二氧六环 、 水 为溶剂， 反应 0.5h， 以73%的产率得到1-[4-N-(9-fluorenylmethoxycarboxyl)aminophenoxy]-3-butene
  参考文献：
  名称：

  Ru(III)-Catalyzed Cyclization of Arene-Alkene Substrates via Intramolecular Electrophilic Hydroarylation

  摘要：

  We herein report that RuCl3/AgOTf has proven to be a hydroarylation catalyst with an efficiency and scope superior to previously known methods. This catalyst demonstrated consistent performance with arene-ene substrates of diverse structural features, providing good to excellent yields of cyclization products (chromanes, tetralins, terpenoids, dihydrocoumarins).

  DOI：

  10.1021/ol036385i
• 作为产物：
  描述：

  4-(BOC-氨基)酚 在 potassium carbonate 、 三氟乙酸 、 sodium iodide 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 24.5h， 生成 4-(3-丁烯-1-基氧基)苯胺
  参考文献：
  名称：

  Ru(III)-Catalyzed Cyclization of Arene-Alkene Substrates via Intramolecular Electrophilic Hydroarylation

  摘要：

  We herein report that RuCl3/AgOTf has proven to be a hydroarylation catalyst with an efficiency and scope superior to previously known methods. This catalyst demonstrated consistent performance with arene-ene substrates of diverse structural features, providing good to excellent yields of cyclization products (chromanes, tetralins, terpenoids, dihydrocoumarins).

  DOI：

  10.1021/ol036385i

文献信息

• Design of postmetallocene catalytic systems of arylimine type for olefi n polymerization: XV. Synthesis of (N-Aryl)salicylaldimine ligands containing a but-3-enyloxy group and their complexes with titanium(IV) dichloride
  作者：I. I. Oleinik、I. V. Oleinik、S. S. Ivanchev、G. A. Tolstikov

  DOI：10.1134/s1070428013080095

  日期：2013.8

  A series of (N-aryl)salicylaldimines was synthesized by the reaction of salicylaldehydes substituted in the positions 3 and 5 by bulky tert-butyl or α-cumyl groups with hydrochlorides of o-, m-, and p-(but-3-enyloxy) aniline in the presence of triethylamine. The obtained compounds formed by the reaction with TiCl2(OPr-i)2 complexes of titanium(IV) dichloride L2TiCl2.

  一系列的（ñ -芳基）水杨醛二胺通过水杨醛在位置取代反应合成3和5由笨重叔丁基或α枯基与盐酸的ø - ，间- ，和p - （丁-3-三乙胺存在下的苯氧基）苯胺。通过与二氯化钛（IV）L 2 TiCl 2的TiCl 2（OPr- i）2配合物反应形成了所获得的化合物。
• Design of postmetallocene catalytic systems of arylimine type for olefin polymerization: XVII. Synthesis of methoxy-substituted (p-aryl)salicylaldimines containing ω-alkenyloxy group, and their complexes with titanium(IV) dichloride
  作者：I. I. Oleinik、I. V. Oleinik、S. S. Ivanchev、G. A. Tolstikov

  DOI：10.1134/s1070428014110050

  日期：2014.11

  Reaction of 5-methoxy-substituted salicylic aldehydes containing in the position 3 tert-butyl, 2-phenylpropan-2-yl, or 1-phenylethyl groups with m- and p-allyloxy-, (but-3-enyloxy)-, (pent-4-enyloxy)anilines without solvent in an open system at 130°C afforded a series of (N-aryl)salicylaldimines L that with TiCl2 (OPr-i)2 formed complexes of titanium(IV) dichloride L2TiCl2.

  在3位叔丁基，2-苯基丙烷-2-基或1-苯基乙基上的5-甲氧基取代的水杨醛与m-和p-烯丙氧基-（but-3-enyloxy）-，（在没有溶剂的情况下，在130°C的开放系统中进行戊-4-烯氧基）苯胺制得的一系列（N-芳基）水杨醛亚胺L与TiCl 2（OPr- i）2形成二氯化钛（IV）L 2 TiCl 2的配合物。
• KLEMARCZYK, PHILIP
  作者：KLEMARCZYK, PHILIP

  DOI：——

  日期：——
• Ru(III)-Catalyzed Cyclization of Arene-Alkene Substrates via Intramolecular Electrophilic Hydroarylation
  作者：So Won Youn、Stefan J. Pastine、Dalibor Sames

  DOI：10.1021/ol036385i

  日期：2004.2.1

  We herein report that RuCl3/AgOTf has proven to be a hydroarylation catalyst with an efficiency and scope superior to previously known methods. This catalyst demonstrated consistent performance with arene-ene substrates of diverse structural features, providing good to excellent yields of cyclization products (chromanes, tetralins, terpenoids, dihydrocoumarins).