2-(4-methoxyphenyl)tellanyl-N-[(2-methylsulfanylphenyl)methyl]ethanamine | 1021490-40-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(4-methoxyphenyl)tellanyl-N-[(2-methylsulfanylphenyl)methyl]ethanamine
• CAS: 1021490-40-3
• 化学式: C₁₇H₂₁NOSTe
• 分子量: 415.026
• InChiKey: ONMOUAZAUFGYHP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.95
• 重原子数：
  21
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  46.6
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  六氟磷酸钾 、 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 2-(4-methoxyphenyl)tellanyl-N-[(2-methylsulfanylphenyl)methyl]ethanamine 以 二氯甲烷 为溶剂， 以63%的产率得到
  参考文献：
  名称：

  Synthesis and single crystal structures of first examples of tridentate ligands of (Te, N, S) type and their complexes with palladium(II), platinum(II) and ruthenium(II)

  摘要：

  The First examples of (Te, N, S) type ligands, 2-CH3SC6H4CH=NCH2CH2TeC6H4-4-OCH3 (L-1) and 2-CH3SC6H4CHNHCH2CH2TeC6H4- 4-OCH3 (L-2), and their metal complexes, [PdCl(L-1)]PF6 center dot CHCl3 0.5H(2)O (4), [PtCl(L-1)] PF6 (5), [PdCl(L-2)] ClO4 center dot CHCl3 (6), [PtCl(L-2)] ClO4 (7), and [Ru(p-cymene)(L-2)](PF6)(2) center dot CHCl3 (8), have been synthesized and characterized. The single crystal structures of 4, 6 and 8 have revealed that both the ligands coordinate in them in a tridentate ( Te, N, S) mode. The geometry around Pd in both the complexes has been found to be square planar, whereas for Ru in a half sandwich complex 8, it is found to be octahedral. Between two molecules of 4 there are intra and inter molecular weak Te center dot center dot center dot Cl [ 3.334(3) and 3.500(3) A, respectively] interactions along with weak intermolecular Pd center dot center dot center dot Te [3.621(2) angstrom] interactions. The Pd-Te bond lengths are between 2.517(6) and 2.541(25) angstrom and the Ru-Te bond length is 2.630(6) angstrom. The crystal structure of [ PdCl2(4-MeO-C6H4-TeCH2CH2NH2)] ( 9) is also determined. It is formed when KPF6 is not added in the synthesis of 4 and Pd-complex of L-1 is recrystallized. Apart from Te center dot center dot center dot Cl secondary interactions, C-H center dot center dot center dot pi interactions also exist in the crystal of 9. (c) 2007 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.09.012
• 作为产物：
  描述：

  N-[2-(4-methoxyphenyl)tellanylethyl]-1-(2-methylsulfanylphenyl)methanimine 在 sodium tetrahydroborate 作用下， 以 乙醇 为溶剂， 以90%的产率得到2-(4-methoxyphenyl)tellanyl-N-[(2-methylsulfanylphenyl)methyl]ethanamine
  参考文献：
  名称：

  苯和三齿（S，N，E）型配体（E = S，Se，Te）设计的酮的转移加氢和钌与半夹心钌配合物的催化氧化（II）

  摘要：

  组合物的复合物FAC - [（η 6 -C 6 H ^ 6）的Ru（大号）] [PF 6 ] [X]（1 - 6 ; X = PF 6或Cl），通过反应形成2- MESC 6 ħ 4 = NCH 2 CH 2 E-C 6 H ^ 4 -4-R（L1 - L3）和2- MESC 6 ħ 4 CH 2 -NHCH 2 CH 2 E-C 6 H ^ 4 -4-R（L4 - L6）（其中，E = S或Se，R = H; E =碲，R = OME）与[{（η 6 -C 6 H ^ 6）的RuCl（μ-Cl）的} 2 ]和NH 4 PF 6，已经其特征在于1 H，13 C { 1 H}，77 Se { 1 H}和125 Te { 1 H} NMR光谱法和X射线晶体学。Ru-Se和Ru-Te键长分别在2.4837（14）-2.4848（14）和2.6234（6）-2.6333（7）Å范围内。配合物1 -

  DOI：

  10.1021/om100807b

文献信息

• Palladium(II) complexes of tridentate chalcogenated Schiff bases and related ligands of (S, N, S/Se/Te) type: Synthesis and structural chemistry
  作者：Pradhumn Singh、Ajai K. Singh

  DOI：10.1016/j.ica.2012.01.007

  日期：2012.5

  The reactions in CH3CN between PdCl2 and Schiff base ligands, 2-MeSC6H4-CH=NCH2CH2E-C6H4-4-R (L1-L3) (E = S or Se, R = H; E = Te, R = OCH3) and their reduced derivatives 2-MeSC6H4CH2-NHCH2CH2E-C6H4-4-R (L4-L6) followed by treatment with AgPF6 or AgClO4 have resulted in complexes [PdCl(L)][ X] (1-6; L = L1-L6; X = PF6 or ClO4) which have been characterized by IR, H-1, C-13H-1}, Se-77H-1} and Te-125H-1} NMR spectroscopy. Single crystal structures of complexes 1-6 reveal nearly square planar geometry around palladium in all of them (Pd-Se = 2.4045(16)-2.4065(6) angstrom; Pd-Te = 2.5052(9)-2.5307(13) angstrom). The various non-covalent interactions in the crystals result in the formation of chains, rings and caging of anions between cations. (C) 2012 Elsevier B.V. All rights reserved.
• Transfer Hydrogenation of Ketones and Catalytic Oxidation of Alcohols with Half-Sandwich Complexes of Ruthenium(II) Designed Using Benzene and Tridentate (S, N, E) Type Ligands (E = S, Se, Te)
  作者：Pradhumn Singh、Ajai K. Singh

  DOI：10.1021/om100807b

  日期：2010.12.13

  and 2.6234(6)−2.6333(7) Å, respectively. Complexes 1−6 have been found to be efficient catalysts for catalytic oxidation of alcohols with N-methylmorpholine-N-oxide, tBuOOH, NaOCl, and NaIO4 and transfer hydrogenation reaction of ketones with 2-propanol. The TON values are up to 9.9 × 104 and 9.8 × 104 for two catalytic processes, respectively. The oxidation probably involves the formation of intermediate

  组合物的复合物FAC - [（η 6 -C 6 H ^ 6）的Ru（大号）] [PF 6 ] [X]（1 - 6 ; X = PF 6或Cl），通过反应形成2- MESC 6 ħ 4 = NCH 2 CH 2 E-C 6 H ^ 4 -4-R（L1 - L3）和2- MESC 6 ħ 4 CH 2 -NHCH 2 CH 2 E-C 6 H ^ 4 -4-R（L4 - L6）（其中，E = S或Se，R = H; E =碲，R = OME）与[（η 6 -C 6 H ^ 6）的RuCl（μ-Cl）的} 2 ]和NH 4 PF 6，已经其特征在于1 H，13 C 1 H}，77 Se 1 H}和125 Te 1 H} NMR光谱法和X射线晶体学。Ru-Se和Ru-Te键长分别在2.4837（14）-2.4848（14）和2.6234（6）-2.6333（7）Å范围内。配合物1 -
• Synthesis and single crystal structures of first examples of tridentate ligands of (Te, N, S) type and their complexes with palladium(II), platinum(II) and ruthenium(II)
  作者：P. Raghavendra Kumar、Shailesh Upreti、Ajai K. Singh

  DOI：10.1016/j.ica.2007.09.012

  日期：2008.4

  The First examples of (Te, N, S) type ligands, 2-CH3SC6H4CH=NCH2CH2TeC6H4-4-OCH3 (L-1) and 2-CH3SC6H4CHNHCH2CH2TeC6H4- 4-OCH3 (L-2), and their metal complexes, [PdCl(L-1)]PF6 center dot CHCl3 0.5H(2)O (4), [PtCl(L-1)] PF6 (5), [PdCl(L-2)] ClO4 center dot CHCl3 (6), [PtCl(L-2)] ClO4 (7), and [Ru(p-cymene)(L-2)](PF6)(2) center dot CHCl3 (8), have been synthesized and characterized. The single crystal structures of 4, 6 and 8 have revealed that both the ligands coordinate in them in a tridentate ( Te, N, S) mode. The geometry around Pd in both the complexes has been found to be square planar, whereas for Ru in a half sandwich complex 8, it is found to be octahedral. Between two molecules of 4 there are intra and inter molecular weak Te center dot center dot center dot Cl [ 3.334(3) and 3.500(3) A, respectively] interactions along with weak intermolecular Pd center dot center dot center dot Te [3.621(2) angstrom] interactions. The Pd-Te bond lengths are between 2.517(6) and 2.541(25) angstrom and the Ru-Te bond length is 2.630(6) angstrom. The crystal structure of [ PdCl2(4-MeO-C6H4-TeCH2CH2NH2)] ( 9) is also determined. It is formed when KPF6 is not added in the synthesis of 4 and Pd-complex of L-1 is recrystallized. Apart from Te center dot center dot center dot Cl secondary interactions, C-H center dot center dot center dot pi interactions also exist in the crystal of 9. (c) 2007 Elsevier B. V. All rights reserved.