acetylpyrroetioporphyrin V | 105658-06-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: acetylpyrroetioporphyrin V
• CAS: 105658-06-8
• 化学式: C₃₂H₃₆N₄O
• 分子量: 492.664
• InChiKey: ZKEZJLKCPYPJNX-PUBUSIHGSA-N

物化性质

• 沸点：
  961.5±60.0 °C(Predicted)
• 密度：
  1.137±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.38
• 重原子数：
  37.0
• 可旋转键数：
  4.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.34
• 拓扑面积：
  74.43
• 氢给体数：
  2.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  acetylpyrroetioporphyrin V 在 sodium tetrahydroborate 、 水 、 苯甲酰氯 、 对甲苯磺酸 、 三乙胺 作用下， 以 乙醇 、 氯仿 、 邻二氯苯 为溶剂， 反应 13.0h， 生成 DPEP
  参考文献：
  名称：

  Bong, Ivy C. C.; Clezy, Peter S.; Fookes, Christopher J. R., Australian Journal of Chemistry, 1993, vol. 46, # 8, p. 1193 - 1206

  摘要：

  DOI：
• 作为产物：
  描述：

  3-ethyl-4,3',5'-trimethyl-4'-acetyl-2,2'-dipyrrylmethane-5-carbaldehyde 在 硫酸 、 copper diacetate 、 sodium acetate 、 溶剂黄146 、 三氟乙酸 作用下， 反应 0.5h， 生成 acetylpyrroetioporphyrin V
  参考文献：
  名称：

  Bong, Ivy C. C.; Clezy, Peter S.; Fookes, Christopher J. R., Australian Journal of Chemistry, 1993, vol. 46, # 8, p. 1193 - 1206

  摘要：

  DOI：

文献信息

• Total synthesis of chlorophyll c fossils and related petroporphyrins
  作者：Claude Bauder、Rubén Ocampo、Henry J. Callot

  DOI：10.1016/s0040-4039(00)74375-9

  日期：1991.11

  The total synthesis of a series of petroporphyrins related to chlorophyll c is described. These compounds have in common, fused to the porphyrin macrocyle, α methylcylopentane ring which was obtained via cyclization of an isopropenyl group.

  描述了与叶绿素c相关的一系列卟啉的全合成。这些化合物通常具有与卟啉大环稠合的α甲基环戊烷环，该环是通过异丙烯基环化获得的。
• Total synthesis of cyclopentenoporphyrins of sedimentary origin: deoxophylloerythroetioporphyrin, chlorophyll c fossils and related compounds.
  作者：Claude Bauder、Rubén Ocampo、Henry J. Callot

  DOI：10.1016/s0040-4020(01)90123-1

  日期：1992.1

  This article describes the total synthesis of seven porphyrins, fossils of chlorophyll derivatives, isolated from sedimentary sources and possess five-membered rings fused to the porphyrin nucleus, this additional ring being placed between positions 13,15 or 15,17. This ring was built from vinyl, hydroxyethyl or isopropenyl groups under strong acidic conditions.
• The Dynamics of Possible Selves in Old Age
  作者：J. Smith、A. M. Freund

  DOI：10.1093/geronb/57.6.p492

  日期：2002.11.1

  Future-oriented motives are thought to be cast off in old age. Transcripts of the hopes and fears of participants in the 4-year longitudinal sample of the Berlin Aging Study (N = 206, 70-100+ years) were coded for central domains and motives (e.g., gain, maintenance, avoiding loss) and evaluated for the amount and direction of change. Domains of personal characteristics, health, and social relationships predominated together with gain motives. Over time, 72% of participants added new domains of hopes and 53% added new fears. Individual differences in stability and change in matched hopes and fears about health and personal identity were associated with changes in physical and functional health. People who added matched possible selves about health, focused on maintenance, and added few new domains of hopes declined in life satisfaction. Overall, these findings indicate that possible selves are a dynamic system during old age.