Acetic acid (R)-10-methyl-7-methylene-3-pentyl-6,7,7a,8,9,11a-hexahydro-5-oxa-dibenzo[a,c]cyclohepten-1-yl ester | 81780-83-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Acetic acid (R)-10-methyl-7-methylene-3-pentyl-6,7,7a,8,9,11a-hexahydro-5-oxa-dibenzo[a,c]cyclohepten-1-yl ester
• CAS: 81780-83-8
• 化学式: C₂₃H₃₀O₃
• 分子量: 354.489
• InChiKey: DHZZHEYDLZYNOE-XJDOXCRVSA-N

反应信息

• 作为产物：
  描述：

  10-bromocannabidiol diacetate 在 氰化钠 作用下， 以 二甲基亚砜 为溶剂， 生成 Acetic acid (R)-10-methyl-7-methylene-3-pentyl-6,7,7a,8,9,11a-hexahydro-5-oxa-dibenzo[a,c]cyclohepten-1-yl ester
  参考文献：
  名称：

  HASHISH:¹SYNTHESIS OF A NOVEL Δ⁹-TETRAHYDROCANNABINOL (THC) ANALOG

  摘要：

  Treatment of cannabinoid diacetate (2b) with N-bromosuccinimide gave the brominated product 2c in excellent yield, which with base formed a novel cannabinoid 3b. The structure was confirmed by 13C n.m.r. and 1H n.m.r. nuclear Overhauser enhancement spectral studies.

  DOI：

  10.1246/cl.1982.299