5,11,17,23-tetra-tert-butyl-25,26,27,28-tetrakis[(3-dihydroxyphosphoryl)-propoxy]calix[4]arene | 847978-61-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetrakis[(3-dihydroxyphosphoryl)-propoxy]calix[4]arene
• CAS: 847978-61-4
• 化学式: C₅₆H₈₄O₁₆P₄
• 分子量: 1137.17
• InChiKey: RGIHTLFXLUHJCQ-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  5,11,17,23-tetra-tert-butyl-25,26,27,28-tetrakis[(3-dihydroxyphosphoryl)-propoxy]calix[4]arene 、 ytterbium(III) nitrate 以 氯仿 、 水 为溶剂， 生成 Yb(III)(5,11,17,23-tetra-tert-butyl-25,26,27,28-tetrakis[(3-dihydroxyphosphoryl)-propoxy]calix[4]arene(3-))
  参考文献：
  名称：

  Synthesis, characterization and extraction behaviour of calix[4]arene with four propylene phosphonic acid groups on the lower rim

  摘要：

  A new calix[4]arene based ligand bearing four phosphonic acid groups was prepared by modification of p-tert-butylcalix[4]arene on the lower rim by bonding with four (CH2)(3)PO(OH)(2) groups. The compound was characterized by NMR spectroscopy. The compound obtained was used as an extractant for certain lanthanide ions (La3+, Eu3+, Yb3+). The extraction experiments were carried out at 25 +/- 2 degreesC and pH 5.5 for 2 h. The formation of the complexes with lanthanide ions was revealed by NMR experiments and luminescence spectroscopy. The extraction efficiencies of the prepared ligand decrease with decreasing radius of the lanthanide ions. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.11.008