[4-[2-(5-Diphenylphosphanyl-2-methylthiophen-3-yl)-3,3,4,4,5,5-hexafluorocyclopenten-1-yl]-5-methylthiophen-2-yl]-diphenylphosphane | 864411-65-4

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: [4-[2-(5-Diphenylphosphanyl-2-methylthiophen-3-yl)-3,3,4,4,5,5-hexafluorocyclopenten-1-yl]-5-methylthiophen-2-yl]-diphenylphosphane
• CAS: 864411-65-4
• 化学式: C₃₉H₂₈F₆P₂S₂
• 分子量: 736.721
• InChiKey: GPEXGXVVGWYBQR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11
• 重原子数：
  49
• 可旋转键数：
  8
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  56.5
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  (tetrahydrothiophene)gold(I) chloride 、 [4-[2-(5-Diphenylphosphanyl-2-methylthiophen-3-yl)-3,3,4,4,5,5-hexafluorocyclopenten-1-yl]-5-methylthiophen-2-yl]-diphenylphosphane 以 二氯甲烷 为溶剂， 生成 [4-[2-(5-diphenylphosphanyl-2-methylthiophen-3-yl)-3,3,4,4,5,5-hexafluorocyclopenten-1-yl]-5-methylthiophen-2-yl]-diphenylphosphane;gold(1+);dichloride
  参考文献：
  名称：

  Synthesis and Coordination Chemistry of a Photoswitchable Bis(phosphine) Ligand

  摘要：

  A 1,2-dithienylethene compound bearing bis(phosphine) groups (1o) represents a new class of photoresponsive ligands where there are steric and electronic differences between two photogenerated isomers. The coordination chemistry of this ligand class is demonstrated by preparing a gold(l) complex (2o) and a phosphine selenide (3o).

  DOI：

  10.1021/ic050429x