l'iodure de 3-ethyl-1,2,3-trimethyl-3H-indolium | 143579-40-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: l'iodure de 3-ethyl-1,2,3-trimethyl-3H-indolium
• 英文别名: 3-ethyl-1,2,3-trimethyl-3H-indolium iodide；3-Ethyl-1,2,3-trimethylindoleninium-iodid；3-ethyl-1,2,3-trimethyl-3H-indolium; iodide；3-Aethyl-1,2,3-trimethyl-3H-indolium; Jodid；2.3-Dimethyl-3-aethyl-indolenin-jodmethylat；3-Ethyl-1,2,3-trimethylindol-1-ium;iodide
• CAS: 143579-40-2
• 化学式: C₁₃H₁₈N*I
• 分子量: 315.197
• InChiKey: YEZMWTRBOSYMPS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.11
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  l'iodure de 3-ethyl-1,2,3-trimethyl-3H-indolium 在 氢氧化钾 作用下， 以 乙醚 、 乙醇 为溶剂， 反应 3.0h， 生成 (3RS,2'RS)(E)-3-ethyl-2,3-dihydro-1,3-dimethyl-2-[(2-methyl-3-nitro)propylidene]-1H-indole
  参考文献：
  名称：

  On the reactivity of some 2-methyleneindolines with β-nitroenamines, α-nitroalkenes, and 1,2-diaza-1,3-butadienes

  摘要：

  A study of the behaviour of some electron-rich 2-methyleneindolines (1-3) with different electron-poor reagents (formation of new carbon-carbon and nitrogen-carbon bonds) has furnished interesting results from both synthetic and the mechanistic viewpoints. Enamines 1-3 have been reacted with the beta-nitroenamines 4-7 (reaction CeCl3 center dot 7H(2)O promoted), giving the polymethine dyes 14-23. The same bases 1-3 have been nitroalkylated with the nitroolefins 8-10, furnishing the indolines 24-32, and the diastereoselectivity of the reaction has been thoroughly investigated. The most unexpected results derived from the first example of reaction of Fischer's bases with 1,2-diaza-1,3-butadienes. In fact, with 11-13, the 'unknown' indoline spirodihydropyrroles 33-40 were formed. Their structures were unambiguously assigned, and we determined, as an example, that of 33 by X-ray analysis. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2006.04.027
• 作为产物：
  描述：

  3-ethyl-2,3-dihydro-1,3-dimethyl-2-methylidene-1H-indole 在 氢碘酸 作用下， 反应 0.25h， 以57%的产率得到l'iodure de 3-ethyl-1,2,3-trimethyl-3H-indolium
  参考文献：
  名称：

  Reichardt, Christian; Engel, Horst-Detlef; Allmann, Rudolf, Chemische Berichte, 1990, vol. 123, p. 565 - 581

  摘要：

  DOI：

文献信息

• Synth�se et propri�t�s photochromiques de 1, 3-dihydrospiro[2H-indole-2,3?-[3H]pyrimido[5,4-f][1,4]benzoxazines] et de 1,3-dihydrospiro[2H-indole-2,7?-[7H]thiazolo[5,4-f][1,4]benzoxazines]
  作者：Pascale Tardieu、Roger Dubest、Jean Aubard、Arlette Kellmann、Francis Tfibel、Andr� Samat、Robert Gugliemetti

  DOI：10.1002/hlca.19920750419

  日期：1992.6.24

  Synthesis and Photochrmic Characteristics of 1,3-Dihydrospiro[2H-indole-2,3′-[3H-]pyrimido[5,4-f][1,4]benzoxazines] and 1,3-Dihydrospiro[2H-indole-2,7′[7H]thiazolo[5,4-f][1,4]benzoxazines]

  的合成和特性Photochrmic 1,3-二氢螺[2H-吲哚-2,3' - [3H-]嘧啶并[5,4-f]的[1,4]苯并恶嗪]和1,3-二氢螺[2 ħ -吲哚-2,7'[7 H ]噻唑洛[5,4- f ] [1,4]苯并恶嗪]
• [EN] HIGH-CAPACITY OPTICAL STORAGE MEDIA<br/>[FR] SUPPORTS DE MÉMOIRE OPTIQUE À GRANDE CAPACITÉ
  申请人：CIBA SC HOLDING AG

  公开号：WO2006018352A1

  公开（公告）日：2006-02-23

  The invention accordingly relates to an optical recording medium comprising a substrate, a reflecting layer and a recording layer, wherein the recording layer comprises a compound of formula (I) or a mesomeric or tautomeric form thereof, wherein M1 is a metal cation in the oxidation state +3, a hydroxy or halogeno metal group wherein the metal is in the oxidation state +4, or an oxo metal group wherein the metal is in the oxidation state +5; (III) and (IV) are each independently of the other (V), (VI) or (VII); (VIII) is (IX), (X), (XI), (XII), (XIII) or (XIV); (XV) is (XVI) or C2-C8 heteroaryl unsubstituted or mono- or poly-substituted by R10, R11, R12 and/or R13; Q1 is N or CR18 , Q2 is N or CR19 , Q3, Q5 and Q7 are each independently of the other CR 20 R 21, O, S or NR22 , Q4 is CR16 or N and Q6 is CR 17 or N ; and R2 and/or R 6 are O, S or NR 33. Please see the disclosure for the other substituents which are less relevant. The compounds of formula (I) are novel and also claimed, as well as the compound of formula (II), or a mesomer or tautomer thereof, wherein R38 is halogen, CF3, NO2, CN, COR22, COOR23 , SO3R23, NCO or SCN, G1, G 2, M1, R1, R2, R4, R5, R6, R8, R22 and R23 are as defined in formula (I), M 2m+ is a cation with m positive charges, and m is an integer 1, 2 or 3. The optical recording media are remarkably suitable for DVD±R (658 nm), especially at high recording speeds.

  该发明涉及一种光学记录介质，包括基板、反射层和记录层，其中所述记录层包括式(I)的化合物或其互变异构体或互变构异体，其中M1是+3氧化态的金属阳离子，氢氧基或卤金属基，其中金属处于+4氧化态，或氧金属基，其中金属处于+5氧化态；(III)和(IV)各自独立于其他(V)、(VI)或(VII)；(VIII)是(IX)、(X)、(XI)、(XII)、(XIII)或(XIV)；(XV)是( XVI)或未经R10、R11、R12和/或R13取代的C2-C8杂环芳基；Q1是N或CR18，Q2是N或CR19，Q3、Q5和Q7各自独立于其他CR20R21、O、S或NR22，Q4是CR16或N，Q6是CR17或N；而R2和/或R6是O、S或NR33。请参阅其他不太相关的取代基的披露。式(I)的化合物是新颖的，并且也被要求，以及式(II)的化合物，或其互变异构体或互变构异体，其中R38是卤素、CF3、NO2、CN、COR22、COOR23、SO3R23、NCO或SCN，G1、G2、M1、R1、R2、R4、R5、R6、R8、R22和R23如式(I)中定义，M2m+是具有m正电荷的阳离子，m是整数1、2或3。这些光学记录介质非常适用于DVD±R（658纳米），尤其在高速记录时。
• Pottier, E.; Sergent, M.; Luu, R. Phan Tan, Bulletin des Societes Chimiques Belges, 1992, vol. 101, # 8, p. 719 - 740
  作者：Pottier, E.、Sergent, M.、Luu, R. Phan Tan、Guglielmetti, R.

  DOI：——

  日期：——
• Koenig; Mueller, Chemische Berichte, 1924, vol. 57, p. 147
  作者：Koenig、Mueller

  DOI：——

  日期：——
• Ciamician; Boeris, Chemische Berichte, 1896, vol. 29, p. 2472
  作者：Ciamician、Boeris

  DOI：——

  日期：——