| 1593201-23-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• CAS: 1593201-23-0
• 化学式: C₆₆H₇₀N₆O₆Pd
• 分子量: 1149.74
• InChiKey: KKFLPPUEJHPPBV-NVNNIDEJSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 三氟乙酸 以 二氯甲烷 为溶剂， 反应 9.5h， 以95%的产率得到
  参考文献：
  名称：

  Sequential and Spatial Organization of Metal Complexes Inside a Peptide Duplex

  摘要：

  To generate integrated organized molecular properties, multiple molecular components are required to be assembled into the molecular system with sequential and spatial accuracy in accordance with the design of the molecular assembly. Herein, we present a novel programmable synthesis of a cofacially stacked porphyrin array via repetitive construction of a peptide duplex. We designed and synthesized a novel porphyrin having two artificial amino acid moieties at the trans meso-positions. The amino acid moieties can be connected with another porphyrin unit by repetitive doubly coupling reactions to afford the peptide duplex bridged by the porphyrins. In the duplex, the porphyrin units are stacked cofacially, and the efficient electronic communication among the arrayed porphyrin units was characterized by split redox waves in the cyclic voltammograms. We also demonstrated the three different square-planar metal ions, namely Cu2+, Ni2+, and Pd2+, were arranged inside the ladder-type porphyrin array in a programmable fashion.

  DOI：

  10.1021/ja502898t
• 作为产物：
  描述：

  bis(acetylacetonato)palladium(II) 、 在 吡啶 作用下， 反应 0.25h， 以92%的产率得到
  参考文献：
  名称：

  Sequential and Spatial Organization of Metal Complexes Inside a Peptide Duplex

  摘要：

  To generate integrated organized molecular properties, multiple molecular components are required to be assembled into the molecular system with sequential and spatial accuracy in accordance with the design of the molecular assembly. Herein, we present a novel programmable synthesis of a cofacially stacked porphyrin array via repetitive construction of a peptide duplex. We designed and synthesized a novel porphyrin having two artificial amino acid moieties at the trans meso-positions. The amino acid moieties can be connected with another porphyrin unit by repetitive doubly coupling reactions to afford the peptide duplex bridged by the porphyrins. In the duplex, the porphyrin units are stacked cofacially, and the efficient electronic communication among the arrayed porphyrin units was characterized by split redox waves in the cyclic voltammograms. We also demonstrated the three different square-planar metal ions, namely Cu2+, Ni2+, and Pd2+, were arranged inside the ladder-type porphyrin array in a programmable fashion.

  DOI：

  10.1021/ja502898t