Mo3S4(diethyldithiophosphate)3(μ-Cl3CCO2)(pyridine) | 398508-29-7

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: Mo3S4(diethyldithiophosphate)3(μ-Cl3CCO2)(pyridine)
• CAS: 398508-29-7
• 化学式: C₁₉H₃₅Cl₃Mo₃NO₈P₃S₁₀
• 分子量: 1213.25
• InChiKey: DXGBXMOAFCOIOC-UHFFFAOYSA-J

反应信息

• 作为反应物：
  描述：

  Mo3S4(diethyldithiophosphate)3(μ-Cl3CCO2)(pyridine) 、 N,N-二甲基甲酰胺 、 对硝基苯甲酸 以 N,N-二甲基甲酰胺 为溶剂， 以65.4%的产率得到Mo3S4(diethyldithiophosphate)3(μ-p-nitrobezoate)(N,N-dimethylformamide)
  参考文献：
  名称：

  Synthesis and X-ray crystal structures of two trinuclear molybdenum clusters coordinated by p-nitrobenzoate: Mo3S4(dtp)3(p-NO2C6H4COO)(L)

  摘要：

  Two new trinuclear molybdenum clusters Mo3S4(dtp)(3)(p-NO2C6H4COO)(L) (dtp = diethyldithiophosphate, L = Py and DMF) have been synthesized by the ligand substitution reaction with p-nitrobenzoic acid using the precursors Mo3S4(dtp)(4)(H2O) and Mo3S4(dtp)(3)(CCl3COO)(Py), respectively. Their structures have been determined by X-ray diffraction analysis and confirmed by P-31 NMR spectra. Both compounds contain [Mo3S4] cores in which three Mo atoms form an isosceles triangle and each Mo atom is octahedrally coordinated. High asymmetry of coordination on the different Mo atoms is observed, The ligand replacement of -dtp by the aromatic acid makes the whole molecule more stable in a dipolar solvent. The coordination difference between Py and DMF also affects the core structure, resulting in the corresponding Mo-Mo distances being different in these two similar cluster compounds. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00862-2