N-(octyl β-D-glucopyranosiduronyl)glycine | 1381777-74-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: N-(octyl β-D-glucopyranosiduronyl)glycine
• 英文别名: 2-[[(2S,3S,4S,5R,6R)-3,4,5-trihydroxy-6-octoxyoxane-2-carbonyl]amino]acetic acid
• CAS: 1381777-74-7
• 化学式: C₁₆H₂₉NO₈
• 分子量: 363.408
• InChiKey: BQDIBIMGJLMPSV-JHZZJYKESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  25
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  146
• 氢给体数：
  5
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  methyl N-(octyl 2,3,4-tri-O-acetyl-β-D-glucopyranosiduronyl)glycinate 在 水 、 sodium hydroxide 作用下， 以 甲醇 为溶剂， 反应 2.0h， 以76%的产率得到N-(octyl β-D-glucopyranosiduronyl)glycine
  参考文献：
  名称：

  Synthesis of new chelating surfactants from octyl d-glucopyranosiduronic acid and amino acids for metal flotation

  摘要：

  A new family of surfactants with metal-chelating properties was synthesized in few steps from octyl D-glucopyranosiduronic acid. The complexing function was either a carboxylic acid or a hydroxamic acid function introduced after coupling with glycine, aspartic acid, or glutamic acid and finally hydroxylamine. Interfacial properties were determined. Flotation experiments on a laboratory scale have been performed with Fe(III) solutions as model contaminant metal. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.carres.2009.12.029

文献信息

• Synthesis of new chelating surfactants from octyl d-glucopyranosiduronic acid and amino acids for metal flotation
  作者：Nadège Ferlin、Diego Grassi、Carlos Ojeda、Mariano J.L. Castro、Eric Grand、Alicia Fernández Cirelli、José Kovensky

  DOI：10.1016/j.carres.2009.12.029

  日期：2010.3

  A new family of surfactants with metal-chelating properties was synthesized in few steps from octyl D-glucopyranosiduronic acid. The complexing function was either a carboxylic acid or a hydroxamic acid function introduced after coupling with glycine, aspartic acid, or glutamic acid and finally hydroxylamine. Interfacial properties were determined. Flotation experiments on a laboratory scale have been performed with Fe(III) solutions as model contaminant metal. (C) 2010 Elsevier Ltd. All rights reserved.