cis-[Co(N-(2-pyridinyl)-P,P-diphenyl-phosphonic amide)2(NO3)][NO3] | 1352132-56-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: cis-[Co(N-(2-pyridinyl)-P,P-diphenyl-phosphonic amide)2(NO3)][NO3]
• CAS: 1352132-56-9
• 化学式: C₃₄H₃₀CoN₅O₅P₂*NO₃
• 分子量: 771.588
• InChiKey: JLNDRSZLLYEFTL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  cis-[Co(N-(2-pyridinyl)-P,P-diphenyl-phosphonic amide)2(NO3)][NO3] 以 neat (no solvent, solid phase) 为溶剂， 生成 cobalt(II) oxide
  参考文献：
  名称：

  Syntheses, structures and ligand conformations of Cu(II), Co(II) and Ag(I) complexes containing the phosphinic amide ligands

  摘要：

  The syntheses, structures and ligand conformations of the complexes trans-Cu(L1)(2)(ClO4)(2), (L1 = N-(2-pyrimidinyl)-P,P-diphenyl-phosphinic amide), 1, [trans-Co(L1)(2)(CH3OH)(2)](ClO4)2 center dot O(C2H5)(2), 2, [trans-Co(L2)(2)(H2O)(2)](ClO4)(2)center dot 2CH(3)OH, (L2 = N-(2-pyridinyl)-P,P-diphenyl-phosphinic amide), 3,]cis-Co(L2)(2) (NO3)](NO3), 4, and [Ag(L3)(NO3)(CH3CN)](infinity), (L3 = N-(6-methyl-2-pyridinyl)-P,P-diphenyl-phosphinic amide), 5, are reported. The L1 and 12 ligands in the monomeric complexes 1-4 chelate the metal centers through the pyrimidyl/pyridyl nitrogen atoms and the phosphinic amide oxygen atoms, whereas the L3 ligands in complex 5 bridge the metal centers, forming a 1-D zigzag chain. The chelating L2 ligands in complexes 3 and 4 adopt cis conformations and the bridging L3 ligand in complex 5 adopts a trans conformation, respectively. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.10.022
• 作为产物：
  描述：

  cobalt(II) nitrate hexahydrate 、 N-(2-pyridinyl)-P,P-diphenylphosphinic acid amide 以 甲醇 为溶剂， 以73%的产率得到cis-[Co(N-(2-pyridinyl)-P,P-diphenyl-phosphonic amide)2(NO3)][NO3]
  参考文献：
  名称：

  Syntheses, structures and ligand conformations of Cu(II), Co(II) and Ag(I) complexes containing the phosphinic amide ligands

  摘要：

  The syntheses, structures and ligand conformations of the complexes trans-Cu(L1)(2)(ClO4)(2), (L1 = N-(2-pyrimidinyl)-P,P-diphenyl-phosphinic amide), 1, [trans-Co(L1)(2)(CH3OH)(2)](ClO4)2 center dot O(C2H5)(2), 2, [trans-Co(L2)(2)(H2O)(2)](ClO4)(2)center dot 2CH(3)OH, (L2 = N-(2-pyridinyl)-P,P-diphenyl-phosphinic amide), 3,]cis-Co(L2)(2) (NO3)](NO3), 4, and [Ag(L3)(NO3)(CH3CN)](infinity), (L3 = N-(6-methyl-2-pyridinyl)-P,P-diphenyl-phosphinic amide), 5, are reported. The L1 and 12 ligands in the monomeric complexes 1-4 chelate the metal centers through the pyrimidyl/pyridyl nitrogen atoms and the phosphinic amide oxygen atoms, whereas the L3 ligands in complex 5 bridge the metal centers, forming a 1-D zigzag chain. The chelating L2 ligands in complexes 3 and 4 adopt cis conformations and the bridging L3 ligand in complex 5 adopts a trans conformation, respectively. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.10.022