(2,6-bis(diphenylphosphoryloxy)1,3,5-triazine)phenothiazine | 811784-75-5

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: (2,6-bis(diphenylphosphoryloxy)1,3,5-triazine)phenothiazine
• 英文别名: 10-[4,6-bis(diphenylphosphoryl)-1,3,5-triazin-2-yl]phenothiazine
• CAS: 811784-75-5
• 化学式: C₃₉H₂₈N₄O₂P₂S
• 分子量: 678.69
• InChiKey: SAHOZHADCGZINL-UHFFFAOYSA-N

物化性质

• 沸点：
  851.6±58.0 °C(Predicted)
• 密度：
  1.43±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.08
• 重原子数：
  48.0
• 可旋转键数：
  7.0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  76.05
• 氢给体数：
  0.0
• 氢受体数：
  7.0

反应信息

• 作为反应物：
  描述：

  (2,6-bis(diphenylphosphoryloxy)1,3,5-triazine)phenothiazine 、 europium(III) trifluoromethanesulfonate 以 乙腈 为溶剂， 生成 (2,6-bis(diphenylphosphoryloxy)1,3,5-triazine)phenothiazine*Eu(III) trifluoromethanesulfonate
  参考文献：
  名称：

  Novel phosphinoxide-bearing ligands and their photoluminescent complexes

  摘要：

  Several novel phosphinoxide ligands have been prepared, based on molecular frameworks: pyridine, 2,2'-bipyridine, cavitands, cyclotriphosphazene and 1,3,5-triazine. These compounds form highly luminescent complexes with Eu(III) and Tb(III). Excellent luminescent properties were observed in case of pyridine and 2,2'-bipyridine ligands with photoluminescence quantum yields approaching 25%. Cavitand-based phosphinoxides turned out to be rather poor sensitisers for the lanthanide ion emission. Particularly long emission lifetime was observed in case of pyridine P-oxide complexes of Eu(III) and Tb(III), exceeding 3 ms. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jallcom.2004.03.051