5,6,14,15-Tetramethoxytetracyclo[8.8.1.03,8.012,17]nonadeca-3,5,7,12,14,16-hexaene | 1135910-59-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 5,6,14,15-Tetramethoxytetracyclo[8.8.1.03,8.012,17]nonadeca-3,5,7,12,14,16-hexaene
• 英文别名: 5,6,14,15-tetramethoxytetracyclo[8.8.1.03,8.012,17]nonadeca-3,5,7,12,14,16-hexaene
• CAS: 1135910-59-6
• 化学式: C₂₃H₂₈O₄
• 分子量: 368.473
• InChiKey: BURCWHXCYHGOEF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  27
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  5,6,14,15-Tetramethoxytetracyclo[8.8.1.03,8.012,17]nonadeca-3,5,7,12,14,16-hexaene 在 亚硝鎓六氯锑酸盐 作用下， 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Molecular Actuator: Redox-Controlled Clam-Like Motion in a Bichromophoric Electron Donor

  摘要：

  The one-electron oxidation of tetra methoxydibenzobicyclo[4.4.1]undecane (4) prompts it to undergo a clam-like electromechanical actuation into a cofacially pi-stacked conformer as established by (1) electrochemical analysis, (ii) by the observation of the intense charge-resonance transition in the near IR region in its cation radical spectrum, and (iii) by X-ray crystallographic characterization of the isolated cation radical salt (4(+center dot) SbCl6-).

  DOI：

  10.1021/ol900371m
• 作为产物：
  描述：

  5,6,14,15-Tetramethoxytetracyclo[8.8.1.03,8.012,17]nonadeca-3,5,7,12,14,16-hexaen-19-one 在 氢氧化钾 、 一水合肼 作用下， 以 二乙二醇 为溶剂， 反应 18.0h， 以81%的产率得到5,6,14,15-Tetramethoxytetracyclo[8.8.1.03,8.012,17]nonadeca-3,5,7,12,14,16-hexaene
  参考文献：
  名称：

  Molecular Actuator: Redox-Controlled Clam-Like Motion in a Bichromophoric Electron Donor

  摘要：

  The one-electron oxidation of tetra methoxydibenzobicyclo[4.4.1]undecane (4) prompts it to undergo a clam-like electromechanical actuation into a cofacially pi-stacked conformer as established by (1) electrochemical analysis, (ii) by the observation of the intense charge-resonance transition in the near IR region in its cation radical spectrum, and (iii) by X-ray crystallographic characterization of the isolated cation radical salt (4(+center dot) SbCl6-).

  DOI：

  10.1021/ol900371m

文献信息

• Molecular Actuator: Redox-Controlled Clam-Like Motion in a Bichromophoric Electron Donor
  作者：Vincent J. Chebny、Ruchi Shukla、Sergey V. Lindeman、Rajendra Rathore

  DOI：10.1021/ol900371m

  日期：2009.5.7

  The one-electron oxidation of tetra methoxydibenzobicyclo[4.4.1]undecane (4) prompts it to undergo a clam-like electromechanical actuation into a cofacially pi-stacked conformer as established by (1) electrochemical analysis, (ii) by the observation of the intense charge-resonance transition in the near IR region in its cation radical spectrum, and (iii) by X-ray crystallographic characterization of the isolated cation radical salt (4(+center dot) SbCl6-).