3,6-Bis[2-[4-[2-[2,5-bis[2-(2,5-didecoxy-4-ethynylphenyl)ethynyl]phenyl]ethynyl]-2,5-didecoxyphenyl]ethynyl]-9-butylcarbazole | 1006046-84-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 3,6-Bis[2-[4-[2-[2,5-bis[2-(2,5-didecoxy-4-ethynylphenyl)ethynyl]phenyl]ethynyl]-2,5-didecoxyphenyl]ethynyl]-9-butylcarbazole
• 英文别名: 3,6-bis[2-[4-[2-[2,5-bis[2-(2,5-didecoxy-4-ethynylphenyl)ethynyl]phenyl]ethynyl]-2,5-didecoxyphenyl]ethynyl]-9-butylcarbazole
• CAS: 1006046-84-9
• 化学式: C₂₀₈H₂₈₉NO₁₂
• 分子量: 2995.58
• InChiKey: BYEIVXIEAREFKM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  75.3
• 重原子数：
  221
• 可旋转键数：
  143
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  116
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  2-[4-[2-[2-[2-[4-[2-[6-[2-[4-[2-[2,5-Bis[2-[2,5-didecoxy-4-(2-trimethylsilylethynyl)phenyl]ethynyl]phenyl]ethynyl]-2,5-didecoxyphenyl]ethynyl]-9-butylcarbazol-3-yl]ethynyl]-2,5-didecoxyphenyl]ethynyl]-4-[2-[2,5-didecoxy-4-(2-trimethylsilylethynyl)phenyl]ethynyl]phenyl]ethynyl]-2,5-didecoxyphenyl]ethynyl-trimethylsilane 在 甲醇 、 potassium carbonate 作用下， 以 四氢呋喃 为溶剂， 反应 3.0h， 以99%的产率得到3,6-Bis[2-[4-[2-[2,5-bis[2-(2,5-didecoxy-4-ethynylphenyl)ethynyl]phenyl]ethynyl]-2,5-didecoxyphenyl]ethynyl]-9-butylcarbazole
  参考文献：
  名称：

  Synthesis of a Nanocar with an Angled Chassis. Toward Circling Movement

  摘要：

  Nanocars with an angled chassis have been synthesized and imaged using scanning tunneling microscopy. These angled chassis nanocars were designed to further our understanding of the directional control and surface-rolling capabilities of this class of nanomachines. The alkylated carbazole inner core might enable the molecular scaffold to produce circular rolling motions of the nanovehicles on surfaces.

  DOI：

  10.1021/ol702642r