(E)-1,2-bis(1,1,3,3,5,5,7,7-octaethyl-s-hydrindacen-4-yl)-1,2-diphenyldisilene | 960079-21-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚满类
• 英文名称: (E)-1,2-bis(1,1,3,3,5,5,7,7-octaethyl-s-hydrindacen-4-yl)-1,2-diphenyldisilene
• 英文别名: (E)-1,2-Bis{(1,1,3,3,5,5,7,7-octaethyl-s-hydrindacene-4-yl)}-1,2-diphenyldisilene；(E)-(1,1,3,3,5,5,7,7-octaethyl-2,6-dihydro-s-indacen-4-yl)-[(1,1,3,3,5,5,7,7-octaethyl-2,6-dihydro-s-indacen-4-yl)-phenylsilylidene]-phenylsilane
• CAS: 960079-21-4
• 化学式: C₆₈H₁₀₀Si₂
• 分子量: 973.713
• InChiKey: QCURHVYYWCIGCX-QNRHEQFBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.76
• 重原子数：
  70
• 可旋转键数：
  20
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  dibromo(1,1,3,3,5,5,7,7-octaethyl-s-hydrindacene-4-yl)phenylsilane 在 naphthalen-1-yl-lithium 作用下， 以 四氢呋喃 为溶剂， 以76%的产率得到(E)-1,2-bis(1,1,3,3,5,5,7,7-octaethyl-s-hydrindacen-4-yl)-1,2-diphenyldisilene
  参考文献：
  名称：

  Coplanar Oligo(p-phenylenedisilenylene)s Based on the Octaethyl-Substituted s-Hydrindacenyl Groups

  摘要：

  The silicon analogues of the oligo(p -phenylenevinylene)s (Si-OPVs) with highly planar structures have been synthesized using a newly developed ligand, the 1,1,3,3,5,5,7,7-octaethyl-s -hydrindacen-4-yl (Eind) group. Their X-ray crystal structures and spectroscopic data demonstrate that the pi-conjugation effectively extends over the Si-OPV framework. Notably, tetrasiladistyrylbenzene exhibits an orange fluorescence even at room temperature both in solution and in the solid state, which is attributable to the effective extension of conjugation. To the best of our knowledge, the tetrasiladistyrylbenzene is the first emissive Si=Si derivative even at room temperature.

  DOI：

  10.1021/ja0764207

文献信息

• Coplanar Oligo(<i>p</i>-phenylenedisilenylene)s Based on the Octaethyl-Substituted <i>s</i>-Hydrindacenyl Groups
  作者：Aiko Fukazawa、Yongming Li、Shigehiro Yamaguchi、Hayato Tsuji、Kohei Tamao

  DOI：10.1021/ja0764207

  日期：2007.11.1

  The silicon analogues of the oligo(p -phenylenevinylene)s (Si-OPVs) with highly planar structures have been synthesized using a newly developed ligand, the 1,1,3,3,5,5,7,7-octaethyl-s -hydrindacen-4-yl (Eind) group. Their X-ray crystal structures and spectroscopic data demonstrate that the pi-conjugation effectively extends over the Si-OPV framework. Notably, tetrasiladistyrylbenzene exhibits an orange fluorescence even at room temperature both in solution and in the solid state, which is attributable to the effective extension of conjugation. To the best of our knowledge, the tetrasiladistyrylbenzene is the first emissive Si=Si derivative even at room temperature.