| 1437793-45-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 香豆素及其衍生物
• CAS: 1437793-45-7
• 化学式: C₂₃H₂₀O₆
• 分子量: 392.408
• InChiKey: ORKWSVGVMVEUOJ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  4-羟基香豆素 、 乙酰乙酸乙酯 、 4-甲氧基苯甲醛 在 3C₁₂H₂₅O₄S^(1-)*Fe⁽³⁺⁾*H₂O 作用下， 以 水 为溶剂， 反应 2.5h， 以70%的产率得到
  参考文献：
  名称：

  Fe(DS)3, an efficient Lewis acid-surfactant-combined catalyst (LASC) for the one pot synthesis of chromeno[4,3-b]chromene derivatives by assembling the basic building blocks

  摘要：

  A highly efficient multicomponent heteroannulation protocol for the synthesis of a library of chromeno[4,3-b]chromene derivative has been developed by applying a Lewis acid-surfactant-combined catalyst (LASC) [Fe(DS)(3)]. The LASC converted the initially floating reaction mass into a homogeneous mixture, which on stirring became a turbid emulsion of colloidal aggregates. The shape and size of the colloidal aggregates are confirmed by optical microscopy and DLS. The aqueous reaction medium, dual role of the catalyst in aqueous media, easy recovery of the catalyst, and high yield make the protocol attractive, sustainable, and economical. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.04.001