Cu(N-(salicylidene)sulfamerazine(1-))(CH3COO)(H2O)(2,2'-bipyridine) | 615540-51-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Cu(N-(salicylidene)sulfamerazine(1-))(CH3COO)(H2O)(2,2'-bipyridine)
• CAS: 615540-51-7
• 化学式: C₃₀H₂₈CuN₆O₆S
• 分子量: 664.201
• InChiKey: DCVRSMKWZNLWNN-ITFXXQIYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 N-(salicylidene)-sulfamerazine 、 copper(II) acetate monohydrate 以 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 以65%的产率得到Cu(N-(salicylidene)sulfamerazine(1-))(CH3COO)(H2O)(2,2'-bipyridine)
  参考文献：
  名称：

  Synthesis and characterization of Mixed‐Ligand Complexes of Cu(II), Ni(II), Co(II), Zn(II), Sm(III), and U(VI)O₂, with a Schiff Base Derived from the Sulfa Drug Sulfamerazine and 2,2′‐Bipyridine

  摘要：

  A new series of novel mixed-ligand complexes of Cu(II), Ni(II), Co(II), Zn(II), Sm(III) and U(VI)O-2 with the Schiff base derived from salicylaldehyde and the sulfa drug sulfamerazine, [N-(salicylidene)-sulfamerazine] (LH) and the heterocyclic base 2,2'-bipyridine (bpy) have been synthesized and characterized by IR, NMR, diffuse reflectance spectra and magnetic, thermal, and molar conductance measurements. The coordination by the azomethine nitrogen is inferred by the downfield shifting of the -CH=N- signal in the NMR spectra and the shift of v(C=N) to lower frequencies by 15-40 cm(-1) in the IR spectra upon complexation. Conductance measurements confirm the non-electrolytic nature of these complexes. The presence of lattice and coordinated water molecules are indicated by thermograms of the complexes. The general compositions of the complexes were found to be [M(L)(bpy)(OAc)(H2O) {where M = Cu(II), Ni(II), Co(II) or Zn(II) and HOAc = acetic acid} and [Sm(L)(bpy)(OAc)(2)(H2O).2H(2)O and [UO2(L)(bpy)(OAc)(H2O).H2O.

  DOI：

  10.1081/sim-120021647