[Pd(TFA)(C6H(t-Bu)2(OP(i-Pr)2)2)] | 1000694-16-5

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: [Pd(TFA)(C6H(t-Bu)2(OP(i-Pr)2)2)]
• CAS: 1000694-16-5
• 化学式: C₂₈H₄₇F₃O₄P₂Pd
• 分子量: 673.042
• InChiKey: GBLIFGULQNELHA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  palladium(II) trifluoroacetate 、 4,6-di-tert-butylresorcinolbis(diisopropylphosphinite) 以 四氢呋喃 为溶剂， 以69%的产率得到[Pd(TFA)(C6H(t-Bu)2(OP(i-Pr)2)2)]
  参考文献：
  名称：

  Simple Palladacyclic and Platinacyclic Catalysts for the 1,4-Conjugate Addition of Arylboronic Acids and Arylsiloxanes to Enones

  摘要：

  A range of palladacyclic, platinacyclic, and pincer-based catalysts have been tested for activity in 1,4-conjugate addition reactions. pi-Acidic palladacycles show excellent activity at room temperature in the reaction of enones with arylboronic acids and reasonable activity when the arylboronic acids are replaced by arylsiloxanes. The X-ray structures of three new palladium kappa(3)-"PCP"-pincer complexes are presented; surprisingly, these complexes show no activity, despite the fact that notionally related phosphine and carbene adducts of palladacycles do.

  DOI：

  10.1021/om700724c