| 1257255-94-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• CAS: 1257255-94-9；1252591-00-6
• 化学式: C₅₈H₇₁MnN₁₂O₂S₄
• 分子量: 1151.48
• InChiKey: GKLJFLNOEDLFAD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  3-(2-diethylaminoethanethiol) phthalonitrile 、 2-二乙氨基乙硫醇 在 manganese(II) acetate 作用下， 反应 12.0h， 以67%的产率得到
  参考文献：
  名称：

  The effects of point of substitution on the electrochemical behavior of new manganese phthalocyanines, tetra-substituted with diethylaminoethanethiol

  摘要：

  The syntheses and comparative studies of the spectral, voltammetry and spectroelectrochemical properties of new manganese phthalocyanine complexes, tetra-substituted with diethylaminoethanethio at the peripheral (complex 3a) and non-peripheral positions (complex 3b) are reported. Solution electrochemistry of complex 3a showed quasi-reversible metal-based ((MnPc-2)-Pc-III/(MnPc-2)-Pc-II, E-1/2 = -0.07 V vs. Ag vertical bar AgCl) and ring-based ((MnPc-2)-Pc-II/MnIIPc-3, E-1/2 = -0.78 V vs. Ag vertical bar AgCl) reductions, but no ring-based oxidation. However, complex 3b showed weak irreversible ring-oxidation signal (Ep = +0.86 vs. Ag vertical bar AgCl). Reversible metal-based ((MnPc-2)-Pc-III/(MnPc-2)-Pc-II, E-1/2 = -0.04 V vs. Ag vertical bar AgCl) and ring-based ((MnPc-2)-Pc-II/MnIIPc-3, E-1/2 = -0.68 V vs. Ag vertical bar AgCl) reductions were also observed for complex 3b. Spectroelectrochemistry was used to confirm these processes. Reduction process involving the metal ((MnPc-2)-Pc-III/(MnPc-2)-Pc-II) was associated with the formation of manganese l-oxo complex in complex 3a. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.06.003