[4-[(3aR,4S,7R,7aS)-1,3-dioxo-3a,4,7,7a-tetrahydro-4,7-epoxyisoindol-2-yl]phenyl] 4-[2-[5-[4-[(3aR,4S,7R,7aS)-1,3-dioxo-3a,4,7,7a-tetrahydro-4,7-epoxyisoindol-2-yl]phenoxy]carbonyl-2-methylthiophen-3-yl]-3,3,4,4,5,5-hexafluorocyclopenten-1-yl]-5-methylthiophene-2-carboxylate | 499204-93-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯烷类
• 英文名称: [4-[(3aR,4S,7R,7aS)-1,3-dioxo-3a,4,7,7a-tetrahydro-4,7-epoxyisoindol-2-yl]phenyl] 4-[2-[5-[4-[(3aR,4S,7R,7aS)-1,3-dioxo-3a,4,7,7a-tetrahydro-4,7-epoxyisoindol-2-yl]phenoxy]carbonyl-2-methylthiophen-3-yl]-3,3,4,4,5,5-hexafluorocyclopenten-1-yl]-5-methylthiophene-2-carboxylate
• CAS: 499204-93-2
• 化学式: C₄₅H₂₈F₆N₂O₁₀S₂
• 分子量: 934.847
• InChiKey: BBOIPKIFGFZDIM-JHGJABPSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  65
• 可旋转键数：
  10
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  202
• 氢给体数：
  0
• 氢受体数：
  18

反应信息

• 作为反应物：
  描述：

  [4-[(3aR,4S,7R,7aS)-1,3-dioxo-3a,4,7,7a-tetrahydro-4,7-epoxyisoindol-2-yl]phenyl] 4-[2-[5-[4-[(3aR,4S,7R,7aS)-1,3-dioxo-3a,4,7,7a-tetrahydro-4,7-epoxyisoindol-2-yl]phenoxy]carbonyl-2-methylthiophen-3-yl]-3,3,4,4,5,5-hexafluorocyclopenten-1-yl]-5-methylthiophene-2-carboxylate 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Novel Photochromic Homopolymers Based on 1,2-Bis(3-thienyl)cyclopentenes

  摘要：

  Incorporation of photochromic molecules into polymer matrices is necessary for materials applications such as optical information processing. Several novel homopolymers were prepared from 1,2-bis(3-thienyl)cyclopentene derivatives using ring-opening metathesis polymerization techniques. Analysis by UV-vis absorption spectroscopy revealed that, in solution, they retained the appealing photochromic behavior exhibited by their respective monomers. The polymers were cast as thin films and spin-coated onto quartz substrates where the solid-state photochromic properties of the polymers were similar to those in solution.

  DOI：

  10.1021/ma0211939
• 作为产物：
  描述：

  exo-3,6-epoxy-1,2,3,6-tetrahydrophthalic anhydride 在 溶剂黄146 、 三乙胺 作用下， 以 二氯甲烷 、 丙酮 为溶剂， 反应 0.17h， 生成 [4-[(3aR,4S,7R,7aS)-1,3-dioxo-3a,4,7,7a-tetrahydro-4,7-epoxyisoindol-2-yl]phenyl] 4-[2-[5-[4-[(3aR,4S,7R,7aS)-1,3-dioxo-3a,4,7,7a-tetrahydro-4,7-epoxyisoindol-2-yl]phenoxy]carbonyl-2-methylthiophen-3-yl]-3,3,4,4,5,5-hexafluorocyclopenten-1-yl]-5-methylthiophene-2-carboxylate
  参考文献：
  名称：

  Novel Photochromic Homopolymers Based on 1,2-Bis(3-thienyl)cyclopentenes

  摘要：

  Incorporation of photochromic molecules into polymer matrices is necessary for materials applications such as optical information processing. Several novel homopolymers were prepared from 1,2-bis(3-thienyl)cyclopentene derivatives using ring-opening metathesis polymerization techniques. Analysis by UV-vis absorption spectroscopy revealed that, in solution, they retained the appealing photochromic behavior exhibited by their respective monomers. The polymers were cast as thin films and spin-coated onto quartz substrates where the solid-state photochromic properties of the polymers were similar to those in solution.

  DOI：

  10.1021/ma0211939

文献信息

• Novel Photochromic Homopolymers Based on 1,2-Bis(3-thienyl)cyclopentenes
  作者：Andrew J. Myles、Neil R. Branda

  DOI：10.1021/ma0211939

  日期：2003.1.1

  Incorporation of photochromic molecules into polymer matrices is necessary for materials applications such as optical information processing. Several novel homopolymers were prepared from 1,2-bis(3-thienyl)cyclopentene derivatives using ring-opening metathesis polymerization techniques. Analysis by UV-vis absorption spectroscopy revealed that, in solution, they retained the appealing photochromic behavior exhibited by their respective monomers. The polymers were cast as thin films and spin-coated onto quartz substrates where the solid-state photochromic properties of the polymers were similar to those in solution.