| 1239498-61-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1239498-61-3
• 化学式: C₂H₃N*C₄₈H₄₄MnN₆O₂S₂
• 分子量: 897.039
• InChiKey: OAUNWXOIXOUUDW-TWVMJPHCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  sodium hydroxide 、 manganese (II) acetate tetrahydrate 、 以 甲醇 、 乙腈 为溶剂， 以63%的产率得到Mn4(μ-2,6-bis(phenylmethyliminomethyl)-4-methylphenolate)2(μ-OH)2(thiocyanate)4
  参考文献：
  名称：

  Reaction Medium pH Dependent Existence of Mn ^II Bound [ON] Donor Zwitterionic Chelating Ligand and Self‐Assembly of Hydroxido‐Bridged Mn ^II ₄ Cluster

  摘要：

  AbstractA mononuclear MnN4O2 complex with two zwitterionic ligands and a centrosymmetric tetranuclear μ3‐OH‐bridged self‐assembled Mn4 cluster were synthesized and characterized by using the [NO(H)N] ligand HOPhbip [2,6‐bis(phenylmethyliminomethyl)‐4‐methylphenol]. The reaction in MeOH in the presence of NH4SCN and a lower stoichiometry of Mn(OAc)2·4H2O without any added base produces [MnII(HNbip)2(NCS)2]·CH3CN (1·CH3CN). In the presence of NaOH and NH4SCN in MeOH, the cluster [MnII4(μ‐bip)2(μ3‐OH)2(NCS)4] (2), featuring a stepped‐cubane, was obtained through hydroxido‐bridge‐driven dimerization of two μ3‐OH‐bridged [Mn2] fragments derived from 1·CH3CN.

  DOI：

  10.1002/ejic.201000170
• 作为产物：
  描述：

  硫氰酸铵 、 2,6-bis(N-benzylformimidoyl)-4-methylphenol 、 manganese (II) acetate tetrahydrate 、 乙腈 以 甲醇 为溶剂， 以74%的产率得到
  参考文献：
  名称：

  Reaction Medium pH Dependent Existence of Mn ^II Bound [ON] Donor Zwitterionic Chelating Ligand and Self‐Assembly of Hydroxido‐Bridged Mn ^II ₄ Cluster

  摘要：

  AbstractA mononuclear MnN4O2 complex with two zwitterionic ligands and a centrosymmetric tetranuclear μ3‐OH‐bridged self‐assembled Mn4 cluster were synthesized and characterized by using the [NO(H)N] ligand HOPhbip [2,6‐bis(phenylmethyliminomethyl)‐4‐methylphenol]. The reaction in MeOH in the presence of NH4SCN and a lower stoichiometry of Mn(OAc)2·4H2O without any added base produces [MnII(HNbip)2(NCS)2]·CH3CN (1·CH3CN). In the presence of NaOH and NH4SCN in MeOH, the cluster [MnII4(μ‐bip)2(μ3‐OH)2(NCS)4] (2), featuring a stepped‐cubane, was obtained through hydroxido‐bridge‐driven dimerization of two μ3‐OH‐bridged [Mn2] fragments derived from 1·CH3CN.

  DOI：

  10.1002/ejic.201000170