bis(dimethylphenylsilylmethyl)(di(2-pyridyl)ketone)palladium(II) | 225931-89-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: bis(dimethylphenylsilylmethyl)(di(2-pyridyl)ketone)palladium(II)
• CAS: 225931-89-5
• 化学式: C₂₉H₃₄N₂OPdSi₂
• 分子量: 589.193
• InChiKey: SSSAENZVAWNNDS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-二吡啶基酮 、 (COD)Pd(CH2SiPhMe2)2 以 乙醚 为溶剂， 以99%的产率得到bis(dimethylphenylsilylmethyl)(di(2-pyridyl)ketone)palladium(II)
  参考文献：
  名称：

  Syntheses and spectroscopic characteristics of dialkylpalladium(II) complexes; PdR2(cod) as precursors for derivatives with N- or P-donor ligands

  摘要：

  Cycloocta-1,5-diene dialkylpalladium(II) derivatives, PdR2(cod), (R = CH2SiMe3, CH2SiMe2Ph) have been isolated and used conveniently as precursors in the preparation of dialkylpalladium complexes, PdR2L2, with N- or P-donor ancillary ligands (R = CH2SiMe3; L-2 = bipy, phen, dppp, dpkt or tmen; L = PMe3; R = CH2SiMe2Ph; L-2 = bipy; dpkt). The complexes Pd(CH2CMe2Ph)(2)(dppe) and PdMe2(bipy) were also prepared from their cyclooctadiene analogues. All have been characterized by H-1-,C-13- and P-31-NMR and IR spectroscopy. (C) 1999 Published by Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)01071-7