24,29-diazadecacyclo[18.12.4.14,8.113,17.03,30.05,29.09,12.016,24.018,23.033,36]octatriaconta-1,3(30),4,6,8(38),13(37),14,16,18(23),19,21,31-dodecaene | 7233-73-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 24,29-diazadecacyclo[18.12.4.14,8.113,17.03,30.05,29.09,12.016,24.018,23.033,36]octatriaconta-1,3(30),4,6,8(38),13(37),14,16,18(23),19,21,31-dodecaene
• CAS: 7233-73-0
• 化学式: C₃₆H₃₂N₂
• 分子量: 492.663
• InChiKey: MRYBBRHDDLHHGJ-UHFFFAOYSA-N

物化性质

• 密度：
  1.841±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  38
• 可旋转键数：
  0
• 环数：
  17.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  9.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  9-[4-[3,6-Bis(ethenyl)carbazol-9-yl]butyl]-3,6-bis(ethenyl)carbazole 以 甲苯 为溶剂， 反应 0.58h， 生成 (9S,12R,33S,36R)-24,29-diazadecacyclo[18.12.4.14,8.113,17.03,30.05,29.09,12.016,24.018,23.033,36]octatriaconta-1,3(30),4,6,8(38),13(37),14,16,18(23),19,21,31-dodecaene 、 24,29-diazadecacyclo[18.12.4.14,8.113,17.03,30.05,29.09,12.016,24.018,23.033,36]octatriaconta-1,3(30),4,6,8(38),13(37),14,16,18(23),19,21,31-dodecaene 、 24,29-diazadecacyclo[18.12.4.14,8.113,17.03,30.05,29.09,12.016,24.018,23.033,36]octatriaconta-1,3(30),4,6,8(38),13(37),14,16,18(23),19,21,31-dodecaene
  参考文献：
  名称：

  Synthesis and Properties of Triply-Bridged syn-Carbazolophanes

  摘要：

  The intramolecular [2 + 2] photocycloaddition of a,omega-bis(3,6-divinyl-N-carbazolyl)alkanes 3 afforded triply bridged syn-[2.2.n] (3,6,9)carbazolophanes 4a-6a (n = 4) and 4b,5b (n = 5) composed of isomers derived from the difference in the direction of cyclobutane rings. In major isomers 4a and 4b, excimer fluorescence was observed, the maximum position remarkably depending on the tether length.

  DOI：

  10.1021/jo026435h

文献信息

• Synthesis and Properties of Triply-Bridged <i>s</i><i>yn</i>-Carbazolophanes
  作者：Yosuke Nakamura、Masayoshi Kaneko、Keita Tani、Teruo Shinmyozu、Jun Nishimura

  DOI：10.1021/jo026435h

  日期：2002.11.1

  The intramolecular [2 + 2] photocycloaddition of a,omega-bis(3,6-divinyl-N-carbazolyl)alkanes 3 afforded triply bridged syn-[2.2.n] (3,6,9)carbazolophanes 4a-6a (n = 4) and 4b,5b (n = 5) composed of isomers derived from the difference in the direction of cyclobutane rings. In major isomers 4a and 4b, excimer fluorescence was observed, the maximum position remarkably depending on the tether length.