3,3'-diaminobenzidinetetracyclohexanoimine[N,N',N",N'"-tetracyclohexylidene-3,4,3',4'-biphenyltetramine] | 753025-33-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,3'-diaminobenzidinetetracyclohexanoimine[N,N',N",N'"-tetracyclohexylidene-3,4,3',4'-biphenyltetramine]
• 英文别名: 3,3'-diaminobenzidinetetracyclohexanoimine；N,N',N'',N'''-tetracyclohexylidene-3,4,3',4'-biphenyltetramine；N-[4-[3,4-bis(cyclohexylideneamino)phenyl]-2-(cyclohexylideneamino)phenyl]cyclohexanimine
• CAS: 753025-33-1
• 化学式: C₃₆H₄₆N₄
• 分子量: 534.788
• InChiKey: VJDCRJXNEXZFBK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  40
• 可旋转键数：
  5
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  49.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3,3'-二氨基联苯胺 、 环己酮 在 氮气 、 环己酮 、 silica gel 作用下， 反应 2.0h， 以to yield 48.1 g (90 mmol) of the target 3,3′-diaminobenzidinetetracyclohexanoimine [N,N′,N″,N′″-tetracyclohexylidene-3,4,3′,4′-biphenyltetramine] in a yield of 90%的产率得到3,3'-diaminobenzidinetetracyclohexanoimine[N,N',N",N'"-tetracyclohexylidene-3,4,3',4'-biphenyltetramine]
  参考文献：
  名称：

  Adamantanetricarboxylic acid derivatives

  摘要：

  本发明提供了一种通过以下公式（1）表示的金刚烷三羧酸衍生物：其中X是氢原子或烃基；R1、R2和R3可能相同也可能不同，且它们分别是一个羧基，该羧基可以由保护基保护，或者是一个羰基卤化物基团，其中至少有一个R1、R2或R3是由保护基保护的羧基，或者是一个羰基卤化物基团。

  公开号：

  US20060264667A1

文献信息

• Adamantanetricarboxylic acid derivatives
  申请人：——

  公开号：US20040242923A1

  公开（公告）日：2004-12-02

  An adamantanetricarboxylic acid derivative is represented by following Formula (1): 1 wherein X is a hydrogen atom or a hydrocarbon group; and R 1 , R 2 and R 3 may be the same as or different from one another and are each a carboxyl group which may be protected by a protecting group, or a carbonyl halide group, wherein at least one of R 1 , R 2 and R 3 is a carboxyl group which is protected by a protecting group, or a carbonyl halide group.

  一种超坚酸衍生物由以下式（1）表示：其中X是氢原子或烃基；R1、R2和R3可以相同也可以不同，分别是一个羧基，可能被保护基保护，或者是羰基卤化物基团，其中至少一个是被保护基保护的羧基，或者是羰基卤化物基团。
• Dielectric films and materials therefor
  申请人：——

  公开号：US20040175858A1

  公开（公告）日：2004-09-09

  A material for dielectric films is a polymerizable composition containing an organic solvent, and an adamantanepolycarboxylic acid derivative represented by following Formula (1): 1 wherein X is hydrogen atom, a hydrocarbon group or R 4 ; R 1 , R 2 , R 3 and R 4 and are each independently a protected or unprotected carboxyl group, etc.; and Y 1 , Y 2 , Y 3 and Y 4 are each independently a single bond or a bivalent aromatic cyclic group; and an aromatic polyamine derivative represented by following Formula ( 2 ): 2 wherein Ring Z is a monocyclic or polycyclic aromatic ring; and R 5 , R 6 , R 7 and R 8 are each a substituent bound to Ring Z and are each independently a protected or unprotected amino group, etc., dissolved in the organic solvent.

  一种用于制备介电薄膜的材料是一种可聚合的组合物，包含有机溶剂和由以下式子（1）表示的金刚烷多羧酸衍生物：1其中X是氢原子、烃基或R4；R1、R2、R3和R4各自独立地是保护或未保护的羧基等；Y1、Y2、Y3和Y4各自独立地是单键或双价芳香环基团；以及由以下式子（2）表示的芳香族多胺衍生物：2其中环Z是单环或多环芳香环；R5、R6、R7和R8各自是结合在环Z上的取代基，各自独立地是保护或未保护的氨基等，溶解在有机溶剂中。
• Dielectric films and materials thereof
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP1462471A1

  公开（公告）日：2004-09-29

  A material for dielectric films is a polymerizable composition containing an organic solvent, and an adamantanepolycarboxylic acid derivative represented by following Formula (1): wherein X is hydrogen atom, a hydrocarbon group or R4; R1, R2, R3 and R4 and are each independently a protected or unprotected carboxyl group, etc.; and Y1, Y2, Y3 and Y4 are each independently a single bond or a bivalent aromatic cyclic group; and an aromatic polyamine derivative represented by following Formula (2): wherein Ring Z is a monocyclic or polycyclic aromatic ring; and R5, R6, R7 and R8 are each a substituent bound to Ring Z and are each independently a protected or unprotected amino group, etc., dissolved in the organic solvent.

  一种用于电介质薄膜的材料是一种可聚合的组合物，其中含有一种有机溶剂和一种金刚烷聚羧酸衍生物，由下式（1）表示： 其中 X 为氢原子、烃基或 R4；R1、R2、R3 和 R4 各自独立地为受保护或未受保护的羧基等；Y1、Y2、Y3 和 Y4 各自独立地为单键或二价芳香环基；以及由下式（2）表示的芳香族多胺衍生物： 其中环 Z 是单环或多环芳香环；R5、R6、R7 和 R8 各自是与环 Z 结合的取代基，且各自独立地是受保护或未受保护的氨基等，溶解在有机溶剂中。
• AROMATIC POLYAMINE DERIVATIVE
  申请人：DAICEL CHEMICAL INDUSTRIES, LTD.

  公开号：EP1681284A1

  公开（公告）日：2006-07-19

  Aromatic polyamine derivatives of this invention are represented by following Formula (1): wherein Ring Z represents a monocyclic or polycyclic aromatic ring; Ra, Rb, Rc, and Rd are each a substituent bonded to Ring Z, where Ra and Rb are the same as or different from each other and each represent a protected or unprotected amino group, and Rc and Rd are the same as or different from each other and each represent a protected or unprotected amino group, a protected or unprotected hydroxy group, or a protected or unprotected mercapto group, and wherein at least one of Ra, Rb, Rc, and Rd represents an amino group protected by an alkylidene group.

  本发明的芳香族多胺衍生物由下式（1）表示： 其中环 Z 代表单环或多环芳香环；Ra、Rb、Rc 和 Rd 各自是与环 Z 键合的取代基，其中 Ra 和 Rb 彼此相同或不同，各自代表受保护或未受保护的氨基，Rc 和 Rd 彼此相同或不同，各自代表受保护或未受保护的氨基、受保护或未受保护的羟基或受保护或未受保护的巯基，且其中 Ra、Rb、Rc 和 Rd 中至少有一个代表受亚烷基保护的氨基。
• Aromatic polyamine derivative
  申请人：Nagano Shinya

  公开号：US20070032556A1

  公开（公告）日：2007-02-08

  Aromatic polyamine derivatives of this invention are represented by following Formula (1): wherein Ring Z represents a monocyclic or polycyclic aromatic ring; R a , R b , R c , and R d are each a substituent bonded to Ring Z, where R a and R b are the same as or different from each other and each represent a protected or unprotected amino group, and R c and R d are the same as or different from each other and each represent a protected or unprotected amino group, a protected or unprotected hydroxy group, or a protected or unprotected mercapto group, and wherein at least one of R a , R b , R c , and R d represents an amino group protected by an alkylidene group.