1,1,2,2,9,9,10,10-octamethyl<2.2>metacyclophan | 93958-99-7

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 二苄基丁烷木脂素
• 英文名称: 1,1,2,2,9,9,10,10-octamethyl<2.2>metacyclophan
• 英文别名: octamethyl<2.2>-m-cyclophane；octamethyl-2,2-metacyclophane；2,2,3,3,9,9,10,10-Octamethyltricyclo[9.3.1.14,8]hexadeca-1(15),4(16),5,7,11,13-hexaene
• CAS: 93958-99-7
• 化学式: C₂₄H₃₂
• 分子量: 320.518
• InChiKey: YBYIICFEWCWDBI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  24
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  sodium;[(E)-(7,7-dimethyl-4-propan-2-ylidene-6-bicyclo[3.2.0]hept-2-enylidene)amino]-(4-methylphenyl)sulfonylazanide 、 二乙二醇二甲醚 以17%的产率得到
  参考文献：
  名称：

  STADLER, H.;REY, M.;DREIDING, A. S., HELV. CHIM. ACTA, 1984, 67, N 5, 1379-1385

  摘要：

  DOI：

文献信息

• Einmeta-Xylylen durchBamford-Stevens-Reaktion eines Fulven-Keten-Addukts
  作者：Heinz Stadler、Max Rey、Andr� S. Dreiding

  DOI：10.1002/hlca.19840670525

  日期：1984.8.8

  A meta-Xylylene by Bamford-Stevens Reaction of a Fulvene-Ketene-Adduct

  一元-Xylylene由班福德-史蒂文斯富烯-乙烯酮加合物的反应
• Generation and Characterization of Alkyl-Substituted m-Xylylenes in Fluid Solution at Room Temperature
  作者：Joseph J. Gajewski、Gitendra C. Paul、Ming Jing Chang、Andrea M. Gortva

  DOI：10.1021/ja00091a018

  日期：1994.6

  Fluoride ion induced generation of isobutylidene from isopropyl trimethylsiiyl ketone enol triflate in the presence of 6,6-dimethylfulvene gives the [2.2]-m-cyclophane dimer of alpha,alpha,alpha'alpha'-tetramethyl-m-xylylene. When isobutylidene is added to 6,6-bis(trideuteriomethyl)fulvene, the C-13 NMR spectrum of the dimer reveals three quaternary carbons in a 1:1:1 ratio, progressively shifted upfield to suggest that two dimers are formed. Saturation of the reactant solutions with dioxygen resulted in no dimer formation despite undiminished loss of reactants. A control experiment indicated that dioxygen does not affect the formation of the methylenecyclopropane from cyclohexene and isobutylidene. Reaction of 6-cyclopropyl-6-methylfulvene with isobutylidene gave dimers with intact cyclopropane rings. Addition of isobutylidene to 6-tert-butyl-6-methylfulvene resulted in a non-cyclophane dimer.
• Generation of a m-xylylene derivative and formation of a 2,2-metacyclophane
  作者：Joseph J. Gajewski、Ming Jing Chang、Peter J. Stang、Thomas E. Fisk

  DOI：10.1021/ja00526a060

  日期：1980.3
• GAJEWSKI J. J.; CHANG M. J.; STANG P. J.; FISK T. E., J. AMER. CHEM. SOC., 1980 , 102, NO 6, 2096-2097
  作者：GAJEWSKI J. J.、 CHANG M. J.、 STANG P. J.、 FISK T. E.

  DOI：——

  日期：——
• Gajewski Joseph J., Paul Gitendra C., Chang Ming Jing, Gortva Andrea M., J. Amer. Chem. Soc, 116 (1994) N 12, S 5150-5154
  作者：Gajewski Joseph J., Paul Gitendra C., Chang Ming Jing, Gortva Andrea M.

  DOI：——

  日期：——