N-salicylideneglycinato-2-methylimidazole-copper(II) | 125896-17-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N-salicylideneglycinato-2-methylimidazole-copper(II)
• CAS: 125896-17-5
• 化学式: C₁₃H₁₃CuN₃O₃
• 分子量: 322.811
• InChiKey: BHLUIPWQMUEPQN-XKYXOGKGSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-甲基咪唑 、 aqua(N-salicylidene-glycinato-O,N,O')copper(II) hemihydrate 以 甲醇 、 水 为溶剂， 生成 N-salicylideneglycinato-2-methylimidazole-copper(II)
  参考文献：
  名称：

  Coordination geometries and cooperative ordering effects in copper(II) complexes with tridentate schiff base dianions—II. EPR study on N-salicylideneglycinatocopper(II) complexes with imidazole derivatives

  摘要：

  N-salicylideneglycinatocopper(II) complexes of the composition Cu(salgly) (L)(H2O)(x) were synthesized with L = 1-methylimidazole, 2-methylimidazole, 2-ethylimidazole, 2-ethyl-4-methylimidazole, 2-phenylimidazole, benzimidazole; and x = 0, 1 or 2. According to the results of ligand-field and EPR spectra, the coordination polyhedra around copper(II) exhibit geometries ranging from square-pyramidal to square-planar. The water of crystallization and the substituents on the imidazole ligand, moreover, remarkably influence cooperative ordering effects. A variety of coupling patterns between ferrodistortive and antiferrodistortive is observed. In some cases enhancement of the EPR measuring frequency from 9 to 35 GHz results in partial decoupling of the systems.

  DOI：

  10.1016/s0277-5387(00)86906-5

文献信息

• Sivy, J.; Kettmann, V.; Kraetsmar-Smogrovic, J., Zeitschrift fur Anorganische und Allgemeine Chemie
  作者：Sivy, J.、Kettmann, V.、Kraetsmar-Smogrovic, J.、Svajlenova, O.、Friebel, C.、Plesch, G.

  DOI：——

  日期：——