5,10,15,20-tetrakis(4-hydroxyphenyl)-21H,23H-porphine-nickel | 107440-85-7

• 分子结构分类: 有机化合物
• 英文名称: 5,10,15,20-tetrakis(4-hydroxyphenyl)-21H,23H-porphine-nickel
• 英文别名: NiTOHPP；[5,10,15,20-tertakis(4-hydroxyphenyl)porphyrinato]Ni(II)；nickel 5,10,15,20-tetrakis(p-hydroxyphenyl) porphyrin；nickel(II) tetrakis(p-hydroxyphenyl)porphyrin
• CAS: 107440-85-7
• 化学式: C₄₄H₂₈N₄NiO₄
• 分子量: 735.421
• InChiKey: FPUUOWFGYJDWDA-DAJBKUBHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  5,10,15,20-tetrakis(4-hydroxyphenyl)-21H,23H-porphine-nickel 、 硝基苯 以 甲醇 、 乙酸乙酯 、 乙腈 为溶剂， 生成 5,10,15,20-tetra(4-hydroxyphenyl)porphyrinatonickel(II) hexa(nitrobenzene)
  参考文献：
  名称：

  Isomorphous free-base, Ni(ii)- and Cu(ii)-5,10,15,20-tetra(4-hydroxyphenyl)porphyrin nitrobenzene hexasolvates with tetragonal 3D hydrogen-bonded network structures

  摘要：

  描述了5,10,15,20-四(4-羟基苯基)-21,23H-卟啉硝基苯六溶剂合物(1)、5,10,15,20-四(4-羟基苯基)卟啉镍(ii)和铜(ii)硝基苯六溶剂合物(2和3)的晶体结构。

  DOI：

  10.1039/c4ce01881h
• 作为产物：
  描述：

  镍 、 5,10,15,20-Tetrakis(4-hydroxyphenyl)porphyrin 以 N,N-二甲基甲酰胺 为溶剂， 生成 5,10,15,20-tetrakis(4-hydroxyphenyl)-21H,23H-porphine-nickel
  参考文献：
  名称：

  Electrochemical metallation with Ni(II) and Al(III) of 5,10,15,20-tetrakis(p-hydroxyphenyl)porphyrin: Effect of ultrasound

  摘要：

  The electrochemical synthesis of Ni(II) and Al(III) metalloporphyrins by reaction of the dianion radical of the 5,10,15,20-tetrakis(p-hydroxyphenyl)porphyrin (TpOHPP) with Ni(II) and Al(III) ions is reported. The electrosynthesis conditions were established by cyclic voltammetry of TpOHPP. The electrosynthesis process was carried out in an undivided cell at the potential corresponding to the formation of the porphyrin dianion radical. A sacrificial anode of Ni or Al was used to electrogenerate the ions. The experiments were carried out in aprotic and protic solvents. The effect of the application of 20 kHz ultrasound on the electrochemical process was evaluated. The electrosynthesis products were characterized by spectroscopy and electrochemical techniques. The results indicate the formation of metalloporphyrins in the different solvents in silent conditions and with ultrasound. The application of 20 kHz ultrasound and protic solvents enhance the reaction yields without affecting the structure of the obtained products. 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.electacta.2013.03.028

文献信息

• One-pot general synthesis of metalloporphyrins
  作者：Anil Kumar、Suman Maji、Prashant Dubey、G.J. Abhilash、Sohini Pandey、Sabyasachi Sarkar

  DOI：10.1016/j.tetlet.2007.08.046

  日期：2007.10

  A new general one-pot method for the synthesis of various metalloporphyrins has been developed from pyrrole and substituted aldehydes using transition metal salts. This method allows higher working concentrations than those previously reported. Along with the reported metalloporphyrins, some new metalloporphyrins were synthesized in good yield.

  已经开发了一种新的通用一锅法，该方法可使用吡咯和取代醛，使用过渡金属盐合成各种金属卟啉。这种方法比以前报道的允许更高的工作浓度。与报道的金属卟啉一起，以高收率合成了一些新的金属卟啉。