[Fe(III)(N,N'-o-phenylenebis(3-ethoxysalicylaldimine)-2H)(H2O)CH3OH)](ClO4) | 1350919-31-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: [Fe(III)(N,N'-o-phenylenebis(3-ethoxysalicylaldimine)-2H)(H2O)CH3OH)](ClO4)
• CAS: 1350919-31-1
• 化学式: C₂₅H₂₈FeN₂O₆*ClO₄
• 分子量: 607.805
• InChiKey: RLTIAUQHNQGVJT-PHNBAMJBSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  甲醇 、 iron perchlorate hexahydrate 、 N,N'-1,2-phenylenebis(3-ethoxysalicylideneamine) 在 triethylamine 作用下， 以 甲醇 、 乙腈 为溶剂， 以85%的产率得到[Fe(III)(N,N'-o-phenylenebis(3-ethoxysalicylaldimine)-2H)(H2O)CH3OH)](ClO4)
  参考文献：
  名称：

  Syntheses, structures, electrochemical measurements and magnetic properties of two iron(III) complexes derived from N,N′-o-phenylenebis(3-ethoxysalicylaldimine)

  摘要：

  The work in this paper presents syntheses, characterizations, crystal structures, electrochemical measurements and magnetic properties of two iron(III) compounds [Fe-III(H2O)(MeOH)](ClO4) (1) and [Fe-III(H2O)(2)](NO3)center dot H2O (2) derived from the Schiff base compartmental ligand N,N'-o-phenylenebis(3-ethoxysalicylaldimine) (H2L). The two compounds are characterized by elemental analyses, IR, electrospray ionization mass (ESI-MS positive), UV-Vis spectra and conductance values. The structures of 1 and 2 show that these are mononuclear compounds having the metal ion in the N2O2 compartment. Two mononuclear moieties in both the compounds are self-assembled due to bifurcated hydrogen bonds involving coordinated water molecule and O(phenoxo)/O(ethoxy) oxygen atoms. The neighboring dimeric self-assemblies in 2 are further interlinked due to hydrogen bonds involving coordinated and solvated water molecules and nitrate anions to generate a one-dimensional topology. Variable-temperature (2-300 K) magnetic susceptibility measurements reveal that iron(III) centers in 1 and 2 belong to high-spin state and there exist weak antiferromagnetic interactions (J = -0.25 cm(-1) for 1 and -0.20 cm(-1) for 2) between the metal centers in the dimeric self-assembly. Cyclic voltammetric and square wave voltammetric studies of the two compounds reveal that compounds 1 and 2 undergo reversible Fe(II)/Fe(III) reduction process at E-Vi = -312 mV and -311 mV, respectively. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2011.09.011