1,6-bis-(4-methoxy-phenyl)-hex-1-ene | 110146-59-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1,6-bis-(4-methoxy-phenyl)-hex-1-ene
• 英文别名: 1,6-Bis-(4-methoxy-phenyl)-hex-1-en；1,6-Bis--hexen-(1)；1-Methoxy-4-[6-(4-methoxyphenyl)hex-1-enyl]benzene
• CAS: 110146-59-3
• 化学式: C₂₀H₂₄O₂
• 分子量: 296.409
• InChiKey: SZJSYKLFFPUHPB-UHFFFAOYSA-N

物化性质

• 熔点：
  93 °C
• 沸点：
  450.5±40.0 °C(Predicted)
• 密度：
  1.026±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.13
• 重原子数：
  22.0
• 可旋转键数：
  8.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  18.46
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  1,6-bis-(4-methoxy-phenyl)-hex-1-ene 在 钯 、 溶剂黄146 作用下， 生成 1-甲氧基-4-[6-(4-甲氧基苯基)己基]苯
  参考文献：
  名称：

  van der Zanden, Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen, Series B: Physical Sciences, 1937, vol. 40, p. 706

  摘要：

  DOI：
• 作为产物：
  描述：

  4-烯丙基苯甲醚 生成 1,6-bis-(4-methoxy-phenyl)-hex-1-ene
  参考文献：
  名称：

  van Romburgh; van der Zanden, Verslag van de Gewone Vergadering van de Afdeling Natuurkunde, Koninklijke Nederlandse Akademie van Wetenschappen, 1917, vol. 25, p. 1303

  摘要：

  DOI：

文献信息

• The elasticity of the exine
  作者：John Rowley、John Skvarla

  DOI：10.1080/00173130150503759

  日期：2000.1

  We pressed pollen grain exines of ten genera with sizes ranging from about 20 to over 100 mu m in diameter past a piston in a close fitting cylinder. The clearance between piston and cylinder was about 20 mu m. Except for exines of Betula all the other pollen types were at least twice the clearance diameter and could be expected to be greatly deformed, crushed or fractured. Cracks were evident with the light microscope in some grains and a few were clearly deformed but most appeared intact, even exines of Zea mays at a diameter of 100-110 mu m. With scanning electron microscopy cracks were apparent in most of the large grains (Zea, Lilium, Pinus, Crinum and Epilobium) but not in the smaller grains (Betula, Ephedra, Tulipa, Fagus and Typha). We also found many exines within exines. In some cases, e.g., Lilium, the exines entered through apertures but in other grains such as Zea and Pinus, exines came in through cracks which had opened during acetolysis or centrifugation, then closed so tightly that the cracks were difficult to see with light microscopy. This opening and closing of cracks in exines means that the pollen grain exine is very flexible and resilient and capable of withstanding shock without permanent deformation. To regain their original form the exine components that were severely cracked, ruptured or partly separated must spring back together like the partly separated halves of a tennis ball.
• van der Zanden, Recueil des Travaux Chimiques des Pays-Bas, 1943, vol. 62, p. 283,287
  作者：van der Zanden

  DOI：——

  日期：——
• van Romburgh, Verslag van de Gewone Vergadering van de Afdeling Natuurkunde, Koninklijke Nederlandse Akademie van Wetenschappen, 1908, vol. 17, p. 972,974
  作者：van Romburgh

  DOI：——

  日期：——
• Smart growth: More than a ghost of urban policy past, less than a bold new horizon
  作者：Robert W. Burchell、David Listokin、Catherine C. Galley

  DOI：10.1080/10511482.2000.9521390

  日期：2000.1