4-butyl-2,6-bis(hydroxymethyl)phenol | 51877-25-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-butyl-2,6-bis(hydroxymethyl)phenol
• 英文别名: 2-Hydroxy-1.3-bis-hydroxymethyl-5-butyl-benzol；4-Butyl-2,6-bis-hydroxymethyl-phenol
• CAS: 51877-25-9
• 化学式: C₁₂H₁₈O₃
• 分子量: 210.273
• InChiKey: PCNDYBPBDAQKME-UHFFFAOYSA-N

物化性质

• 熔点：
  67.0-67.4 °C
• 沸点：
  367.5±11.0 °C(Predicted)
• 密度：
  1.159±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  60.7
• 氢给体数：
  3
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-butyl-2,6-bis(hydroxymethyl)phenol 生成 聚合甲醛 、 水
  参考文献：
  名称：

  Hanus; Fuchs, Journal fur praktische Chemie (Leipzig 1954), 1939, vol. <2> 153, p. 327,335

  摘要：

  DOI：
• 作为产物：
  描述：

  聚合甲醛 、 4-丁基苯酚 在 sodium hydroxide 作用下， 生成 4-butyl-2,6-bis(hydroxymethyl)phenol
  参考文献：
  名称：

  Hanus; Fuchs, Journal fur praktische Chemie (Leipzig 1954), 1939, vol. <2> 153, p. 327,335

  摘要：

  DOI：

文献信息

• Inclusion Properties of Acyclic<i>p</i>-Substituted Phenol–Formaldehyde Oligomers
  作者：Tyo Sone、Yoshihiro Ohba、Hajime Yamazaki

  DOI：10.1246/bcsj.62.1111

  日期：1989.4.15

  Acyclic para-substituted phenol–formaldehyde oligomers (R=H, Me, n-Bu, t-Bu, and cyclohexyl; the number of phenol units=3–6) form host–guest complexes with various organic compounds. The inclusion property of the acyclic oligomers is greatly influenced by the p-substituents of phenol and the number of phenol units in the oligomers; for example, a) while the t-butyl tetramer is effective, the corresponding butyl tetramer has a poor ability for the complex formation, and b) the tetramers and pentamers are good hosts for organic compounds, forming 2:1 (host:guest) complexes in many cases.

  非环状对取代的酚-甲醛低聚物（R=H, Me, n-Bu, t-Bu 和环己基；酚单位数量=3-6）与各种有机化合物形成宿主- guest 复合物。非环状低聚物的包容特性受到酚的对位取代基和低聚物中酚单位数量的显著影响；例如，a) 尽管叔丁基四聚物表现有效，但对应的正丁基四聚物在复合物形成方面能力较差，b) 四聚物和五聚物对有机化合物是良好的宿主，在许多情况下形成2:1（宿主: guest）复合物。
• Photosensitive resin composition, method for manufacturing cured relief pattern, and semiconductor apparatus
  申请人：ASAHI KASEI KABUSHIKI KAISHA

  公开号：US10831101B2

  公开（公告）日：2020-11-10

  A photosensitive resin composition containing a resin and a compound each having a structure specified by the present specification provides a cured film having excellent adhesiveness to copper wiring.

  一种光敏树脂组合物含有一种树脂和一种化合物，每种树脂和化合物都具有本说明书规定的结构，这种组合物提供的固化薄膜对铜线具有极佳的粘合性。
• Resin composition
  申请人：TORAY INDUSTRIES, INC.

  公开号：US10990008B2

  公开（公告）日：2021-04-27

  The present invention provides a resin composition which can result in a cured film which has chemical resistance, low stress property, and high elongation property even by a heat treatment at a low temperature. The resin composition comprising an alkali-soluble resin (a) which contains a phenol skeleton having a crosslinking group and a phenol skeleton not having a crosslinking group and which has a weight average molecular weight in the range of 1,000 to 50,000, wherein the content ratio of the phenol skeleton having a crosslinking group to the total 100% by mole of structural units of the phenol skeleton having a crosslinking group and the phenol skeleton not having a crosslinking group is in the range of 5 to 90% by mole.

  本发明提供了一种树脂组合物，即使在低温下进行热处理，也能形成具有耐化学性、低应力特性和高伸长特性的固化膜。 该树脂组合物包括碱溶性树脂 (a)，它含有具有交联基团的苯酚骨架和不具有交联基团的苯酚骨架，其重量平均分子量在 1,000 至 50,000 之间，其中具有交联基团的苯酚骨架与具有交联基团的苯酚骨架和不具有交联基团的苯酚骨架的结构单元总数的 100%（以摩尔计）的含量比在 5 至 90%（以摩尔计）之间。
• SONE, TYO;OHBA, YOSHIHIRO;YAMAZAKI, HAJIME, BULL. CHEM. SOC. JAP., 62,(1989) N, C. 1111-1116
  作者：SONE, TYO、OHBA, YOSHIHIRO、YAMAZAKI, HAJIME

  DOI：——

  日期：——
• NOVEL BIS-(HYDROXYBENZALDEHYDE) COMPOUND AND NOVEL POLYNUCLEAR POLYPHENOL COMPOUND DERIVED THEREFROM AND METHOD FOR PRODUCTION THEREOF
  申请人：Yoshitomo Akira

  公开号：US20090076310A1

  公开（公告）日：2009-03-19

  Provide a new bis-(hydroxybenzaldehyde) compound, as well as a new polynuclear polyphenol compound derived therefrom, suitable for use as component materials for photosensitive resist compositions, component materials and hardeners for epoxy resins, developers and anti-fading agents used in thermosensitive recording materials, bactericides, fungicides, antioxidants and other functional chemical products or component materials thereof, wherein such bis-(hydroxybenzaldehyde) compound is produced by reacting in the presence of trihalogenated acetic acid catalyst or phosphoric acid catalyst a 2,6-di(hydroxymethyl)-4-alkylphenol with a hydroxybenzaldehyde expressed by general formula (14).