(Z)-13-hexadecenyl acetate | 56218-74-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (Z)-13-hexadecenyl acetate
• 英文别名: (Z)-hexadec-13-en-1-yl acetate；[(Z)-hexadec-13-enyl] acetate
• CAS: 56218-74-7
• 化学式: C₁₈H₃₄O₂
• 分子量: 282.467
• InChiKey: FBDAKDSWNVUHKR-PLNGDYQASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  20
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  二甲基二硫 、 (Z)-13-hexadecenyl acetate 在 碘 作用下， 以 乙醚 、 正己烷 为溶剂， 生成 Acetic acid 13,14-bis-methylsulfanyl-hexadecyl ester
  参考文献：
  名称：

  Determination of double bond position in mono-unsaturated acetates by mass spectrometry of dimethyl disulfide adducts

  摘要：

  DOI：

  10.1021/ac00257a003

文献信息

• MICROORGANISMS FOR THE PRODUCTION OF INSECT PHEROMONES AND RELATED COMPOUNDS
  申请人：Provivi, Inc.

  公开号：EP3635124A1

  公开（公告）日：2020-04-15
• [EN] MICROORGANISMS FOR THE PRODUCTION OF INSECT PHEROMONES AND RELATED COMPOUNDS<br/>[FR] MICRO-ORGANISMES DESTINÉS À LA PRODUCTION DE PHÉROMONES D'INSECTES ET COMPOSÉS ASSOCIÉS
  申请人：PROVIVI INC

  公开号：WO2018213554A1

  公开（公告）日：2018-11-22

  The present application relates to recombinant microorganisms useful in the biosynthesis of unsaturated C6-C24 fatty alcohols, aldehydes, and acetates which may be useful as insect pheromones, fragrances, flavors, and polymer intermediates. The recombinant microorganisms may express enzymes or enzyme variants useful for production of and/or may be modified to down regulate pathways to shunt production toward unsaturated C6-C24 fatty alcohols, aldehydes, and acetates. The C6-C24 fatty alcohols, aldehydes, and acetates described herein may be used as substrates for metathesis reactions to expand the repertoire of target compounds and pheromones. Also provided are methods of producing unsaturated C6-C24 fatty alcohols, aldehydes, and acetates using the recombinant microorganisms, as well as compositions comprising the recombinant microorganisms and/or optionally one or more of the product alcohols, aldehydes, or acetates.
• Determination of double bond position in mono-unsaturated acetates by mass spectrometry of dimethyl disulfide adducts
  作者：Hans Rudolf. Buser、Heinrich. Arn、Patrick. Guerin、Stefan. Rauscher

  DOI：10.1021/ac00257a003

  日期：1983.5.1