phosphonic acid ethyl ester hexyl ester | 5958-38-3

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: phosphonic acid ethyl ester hexyl ester
• 英文别名: phosphorous acid ethyl ester hexyl ester；Ethyl-hexyl-phosphit；Ethyl hexyl hydrogen phosphite
• CAS: 5958-38-3
• 化学式: C₈H₁₉O₃P
• 分子量: 194.211
• InChiKey: BFPRYLBUWNNPMW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  12
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  38.7
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  phosphonic acid ethyl ester hexyl ester 在 磺酰氯 作用下， 以 四氯化碳 为溶剂， 生成 n-hexyl chlorophosphonate ethyl ester
  参考文献：
  名称：

  Maklyaev,F.L. et al., Journal of general chemistry of the USSR, 1962, vol. 32, p. 3357 - 3360

  摘要：

  DOI：
• 作为产物：
  描述：

  Hexyldichlorphosphit 、 乙醇 生成 phosphonic acid ethyl ester hexyl ester
  参考文献：
  名称：

  Maklyaev,F.L. et al., Journal of general chemistry of the USSR, 1962, vol. 32, p. 3357 - 3360

  摘要：

  DOI：

文献信息

• Lubricating oil composition
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0316610A1

  公开（公告）日：1989-05-24

  Lubricating oil composition which comprises: lubricating base oil, (A) at least one organophosphorus compound represented by the general formula (I), (II), (III), (IV), (V), (VI), (VII) or (VIII) and (B) at least one organomolybdenum compound selected from the group consisting of molybdenum oxysulfide alkylphosphoro­dithioates and molybdenum oxysulfide alkyldithiocarbamates. The lubricating oil composition is excellent in antiwear properties, anti-seizure properties, and corrosion resistance, and is suitable for gear oils, and bearing oils, also for internal combustion engine oils and automatic transmission fluids, and further for hydraulic fluids, metal working fluids.

  润滑油组合物，其中包括 润滑基础油、 (A) 至少一种由通式(I)、(II)、(III)、(IV)、(V)、(VI)、(VII)或(VIII)代表的有机磷化合物 和 (B) 至少一种选自二硫代磷酸钼烷基酯和二硫代氨基甲酸钼烷基酯的有机钼化合物。 这种润滑油组合物具有优异的抗磨性、抗震性和耐腐蚀性，适用于齿轮油和轴承油，也适用于内燃机油和自动传动液，还适用于液压油和金属加工液。
• Selective inorganic catalysts in the form of molecular imprints in cavities
  申请人：Studiengesellschaft Kohle mbH

  公开号：EP0619141A1

  公开（公告）日：1994-10-12

  The present invention relates to a process for producing inorganic solids as catalysts which contain imprints of molecules in the form of cavities, which molecules in their three-dimensional structures conform to intermediates or transition states of chemical reactions to be catalyzed, characterized in that inorganic or organometal monomer units are polymerized in the presence of the molecules to be imprinted, wherein the molecules to be imprinted have been chemically bonded to anchor groups (mo nomer units) and are admixed prior to or in the beginning of the polymerization process and the imprinted molecules are subsequently removed after the polymerization, to the resulting catalysts and to the use thereof.

  本发明涉及一种生产作为催化剂的无机固体的工艺，该催化剂含有空穴形式的分子印记，这些分子在其三维结构中符合待催化化学反应的中间体或过渡态，其特征在于无机或有机金属单体单元在待印记分子的存在下聚合、其中，待压印分子已与锚基（单体单元）化学键合，并在聚合过程之前或开始时混入，随后在聚合之后将压印分子移除，从而得到催化剂及其用途。
• PROCESSES FOR PRODUCING POLYOXYALKYLENE POLYOL AND PRODUCING DERIVATIVE THEREOF
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1041100A1

  公开（公告）日：2000-10-04

  The object is to provide a method for producing a polyoxyalkylene polyol and a method for producing a derivative thereof wherein the remaining catalyst compound is efficiently removed from a crude polyoxyalkylene polyol by a simple manner, and a method for producing a polyoxyalkylene polyol wherein a crude polyoxyalkylene polyol is produced by addition polymerization of an epoxide compound to an active hydrogen compound using as a catalyst a compound having a P=N bond, then, the crude polyoxyalkylene polyol is allowed to contact with a solid acid having a specific surface area of 450 to 1200 m2/g and an average pore diameter of 40 to 100 Å to control the catalyst-remaining amount in the polyoxyalkylene polyol to 150 ppm or less, and a method for producing a derivative of the-above-described polyol are provided.

  本发明的目的是提供一种生产聚氧亚烷基多元醇及其衍生物的方法，在该方法中，剩余的催化剂化合物能以简单的方式从粗聚氧亚烷基多元醇中有效地除去，以及一种生产聚氧亚烷基多元醇的方法，在该方法中，粗聚氧亚烷基多元醇是通过环氧化合物与活性氢化合物的加成聚合制得的，使用的催化剂是具有P=N键的化合物、然后，让粗聚氧亚烷基多元醇与比表面积为 450 至 1200 m2/g、平均孔径为 40 至 100 Å 的固体酸接触，以将聚氧亚烷基多元醇中的催化剂残留量控制在 150 ppm 或以下，本发明还提供了一种生产上述多元醇衍生物的方法。
• LUBRICATING OIL COMPOSITION FOR DIE FORGING AND DIE FORGING DEVICE
  申请人：Mitsubishi Heavy Industries, Ltd.

  公开号：EP2492336A1

  公开（公告）日：2012-08-29

  Provided is a lubricating oil composition for die forging which has excellent lubricity. Also provided is a die forging device which is suitable also for the lubricating oil composition for die forging. The lubricating oil composition for die forging comprises at least two solid lubricants differing in particle diameter, an extreme-pressure additive, and a base oil as the remainder. The die forging device comprises: a pair of dies, an upper die and a lower die, that is for sandwiching therebetween a material to be forged and forming the material; and a lubricating-oil-composition sprayer for spraying the lubricating oil composition for die forging over the surfaces of the dies. The lubricating-oil-composition sprayer is equipped with an oil supply tank in which the lubricating oil composition for die forging is stored and a supply pipe for sucking up the lubricating oil composition for die forging from the oil supply tank and supplying the composition to a nozzle, the supply pipe having a plurality of suction ports.

  本发明提供了一种模锻用润滑油组合物，它具有极佳的润滑性。同时还提供了一种模锻装置，该装置也适用于模锻用润滑油组合物。模锻用润滑油组合物包括至少两种颗粒直径不同的固体润滑剂、一种极压添加剂和一种作为余量的基础油。模锻装置包括：一对模具，即上模和下模，用于将待锻材料夹在中间并形成材料；以及一个润滑油组合物喷雾器，用于在模具表面喷洒模锻用润滑油组合物。润滑油成分喷雾器配备有一个供油箱，其中储存有用于模锻的润滑油成分；以及一个供油管，用于从供油箱中吸入用于模锻的润滑油成分，并将该成分供应给一个喷嘴，该供油管具有多个吸入口。
• POLYOL, POLYOL COMPOSITION, AND SOFT POLYURETHANE FOAM COMPRISING THE COMPOSITION
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2602275A1

  公开（公告）日：2013-06-12

  Disclosed are a polyol with a molecular weight distribution Mw/Mn of 4 or more, obtained by reacting a compound comprising an alkylene oxide compound (II) having a hydroxyl group in a base polyol (I) with a molecular weight of 2000 or more; and a polyol composition for a flexible polyurethane foam, comprising a polyol compound and a crosslinker, wherein the crosslinker comprises a polyol (a) with a hydroxyl value of 50 to 1100 mgKOH/g and with a primary hydroxylate ratio of 25 % or more and 60 % or less, which is obtained by an addition of a compound comprising alkylene oxide compound (ii) having a hydroxyl group to active hydrogen compound (i).

  本发明公开了一种分子量分布 Mw/Mn 为 4 或更高的多元醇，该多元醇是通过将包含具有羟基的环氧亚 烷化合物 (II) 的化合物与分子量为 2000 或更高的基础多元醇 (I) 反应而得到的；一种用于软质聚氨酯泡沫塑料的多元醇组合物，包括多元醇化合物和交联剂，其中交联剂包括一种多元醇 (a)，其羟基值为 50 至 1100 mgKOH/g，伯羟基比为 25 % 或以上且 60 % 或以下，该多元醇是通过将包含具有羟基的环氧亚烷基化合物(ii)的化合物添加到活性氢化合物(i)中获得的。