copper(II) tetrapyrazinoporphyrazine | 26603-03-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: copper(II) tetrapyrazinoporphyrazine
• 英文别名: Cu tetrapyrazinoporphyrazine；CuPTpz；Copper;2,5,8,11,14,17,20,23,26,29,32,35,37,39-tetradecaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13,15,17,19(39),20,22,24,26,28,30(37),31,33,35-nonadecaene；copper;2,5,8,11,14,17,20,23,26,29,32,35,37,39-tetradecaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13,15,17,19(39),20,22,24,26,28,30(37),31,33,35-nonadecaene
• CAS: 26603-03-2
• 化学式: C₂₄H₈CuN₁₆
• 分子量: 583.981
• InChiKey: KNVOIULZFFCSHB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.28
• 重原子数：
  41
• 可旋转键数：
  0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  179
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  copper(II) tetrapyrazinoporphyrazine 在 氯化亚砜 、 lithium tetrachloroaluminate 作用下， 生成 CuPTpz*SOCl2
  参考文献：
  名称：

  Effect of N atoms in the backbone of metal phthalocyanine derivatives on their catalytic activity to lithium battery

  摘要：

  Metal phthalocyanine (MPc, M = Mn2+, Fe2+, Co2+, Ni2+ and Cu2+). metal tetrapyridinoporphyrazine, and metal tetrapyrazinoporphyrazine are synthesized by microwave reaction and characterized by elemental analyzer, IR spectroscopy and UV-vis spectroscopy. The catalytic activity of MPc derivatives to Li/SOCl2 battery is evaluated by the relative discharge energy of the battery whose electrolyte contains the compounds. The discharge energy of Li/SOCl2 battery catalyzed by MPc is approximately 0-61% higher than that of Li/SOCl2 battery in the absence of compounds, depending on the central metal ion. To the same central metal ion, the discharge energy of Li/SOCl2 battery catalyzed by MTAP is approximately 60% higher than that by MPc. The discharge energy of Li/SOCl2 battery in which SOCl2 contains MPTpz is approximately 17-19% higher than that of the battery in the absence Of compounds, and almost independent of central metal ions. It shows a correlation existing between the Structure and the catalytic active sites of MPc derivatives. The double active site model is proposed to interpret the results. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2009.11.014
• 作为产物：
  描述：

  2,3-二氰基吡嗪 、 copper(II) choride dihydrate 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 、 四聚乙二醇单月桂醚 、 十六烷基三甲基氯化铵 作用下， 以 甲醇 、 正己烷 为溶剂， 反应 0.33h， 以45mg的产率得到copper(II) tetrapyrazinoporphyrazine
  参考文献：
  名称：

  テトラアザポルフィリン化合物ナノ粒子の製造方法、並びに該ナノ粒子を用いた着色組成物、分散インキ、およびカラーフィルタ

  摘要：

  【问题】提供一种制造高纯度四氮杂卟啉化合物的方法，它具有小的纵横比，均匀的形状，鲜艳的蓝色和优异的耐光性，在580nm附近具有强烈的吸收。 【解决方案】包括以下步骤：合成四氮杂卟啉前体，在含有氮的复杂环状化合物和碱性催化剂的有机溶剂溶液中照射紫外线；形成混合了非离子表面活性剂、离子表面活性剂、有机溶剂、四氮杂卟啉前体和金属盐的胶束；对胶束进行紫外线照射，形成颜料颗粒。该方法由式（1）表示。 【附图】图1

  公开号：

  JP2018053134A
• 作为试剂：
  描述：

  氯化亚砜 在 copper(II) tetrapyrazinoporphyrazine LiAlCl₄ 作用下， 以 水 为溶剂， 生成 二氧化硫 、 sulfur
  参考文献：
  名称：

  Effect of N atoms in the backbone of metal phthalocyanine derivatives on their catalytic activity to lithium battery

  摘要：

  Metal phthalocyanine (MPc, M = Mn2+, Fe2+, Co2+, Ni2+ and Cu2+). metal tetrapyridinoporphyrazine, and metal tetrapyrazinoporphyrazine are synthesized by microwave reaction and characterized by elemental analyzer, IR spectroscopy and UV-vis spectroscopy. The catalytic activity of MPc derivatives to Li/SOCl2 battery is evaluated by the relative discharge energy of the battery whose electrolyte contains the compounds. The discharge energy of Li/SOCl2 battery catalyzed by MPc is approximately 0-61% higher than that of Li/SOCl2 battery in the absence of compounds, depending on the central metal ion. To the same central metal ion, the discharge energy of Li/SOCl2 battery catalyzed by MTAP is approximately 60% higher than that by MPc. The discharge energy of Li/SOCl2 battery in which SOCl2 contains MPTpz is approximately 17-19% higher than that of the battery in the absence Of compounds, and almost independent of central metal ions. It shows a correlation existing between the Structure and the catalytic active sites of MPc derivatives. The double active site model is proposed to interpret the results. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2009.11.014

文献信息

• Effect of N atoms in the backbone of metal phthalocyanine derivatives on their catalytic activity to lithium battery
  作者：Zhanwei Xu、Guoxiang Zhang、Zeyuan Cao、Jianshe Zhao、Hejun Li

  DOI：10.1016/j.molcata.2009.11.014

  日期：2010.3.1

  Metal phthalocyanine (MPc, M = Mn2+, Fe2+, Co2+, Ni2+ and Cu2+). metal tetrapyridinoporphyrazine, and metal tetrapyrazinoporphyrazine are synthesized by microwave reaction and characterized by elemental analyzer, IR spectroscopy and UV-vis spectroscopy. The catalytic activity of MPc derivatives to Li/SOCl2 battery is evaluated by the relative discharge energy of the battery whose electrolyte contains the compounds. The discharge energy of Li/SOCl2 battery catalyzed by MPc is approximately 0-61% higher than that of Li/SOCl2 battery in the absence of compounds, depending on the central metal ion. To the same central metal ion, the discharge energy of Li/SOCl2 battery catalyzed by MTAP is approximately 60% higher than that by MPc. The discharge energy of Li/SOCl2 battery in which SOCl2 contains MPTpz is approximately 17-19% higher than that of the battery in the absence Of compounds, and almost independent of central metal ions. It shows a correlation existing between the Structure and the catalytic active sites of MPc derivatives. The double active site model is proposed to interpret the results. (C) 2009 Elsevier B.V. All rights reserved.
• テトラアザポルフィリン化合物ナノ粒子の製造方法、並びに該ナノ粒子を用いた着色組成物、分散インキ、およびカラーフィルタ
  申请人：山本化成株式会社

  公开号：JP2018053134A

  公开（公告）日：2018-04-05

  【課題】アスペクト比が小さく、均一な形状で、鮮明な青色で耐光性に優れ、５８０ｎｍ附近に強い吸収をもつ高純度なテトラアザポルフィン化合物の製造方法の提供。【解決手段】Ｎ含有複素環化合物及び塩基性触媒を含む有機溶媒溶液に紫外線を照射するテトラアザポルフィン前躯体の合成工程、ノニオン性界面活性剤、イオン性界面活性剤、有機溶媒、テトラアザポルフィン前躯体、及び金属塩を混合するミセルの形成工程、ミセルに対して紫外線照射する顔料粒子形成工程を備える式（１）で表されるテトラアザポルフィリン顔料粒子の製造方法。【選択図】図１

  【问题】提供一种制造高纯度四氮杂卟啉化合物的方法，它具有小的纵横比，均匀的形状，鲜艳的蓝色和优异的耐光性，在580nm附近具有强烈的吸收。 【解决方案】包括以下步骤：合成四氮杂卟啉前体，在含有氮的复杂环状化合物和碱性催化剂的有机溶剂溶液中照射紫外线；形成混合了非离子表面活性剂、离子表面活性剂、有机溶剂、四氮杂卟啉前体和金属盐的胶束；对胶束进行紫外线照射，形成颜料颗粒。该方法由式（1）表示。 【附图】图1