N-methyl-1-(2,4,6-trimethylphenyl)methanimine | 53699-37-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-methyl-1-(2,4,6-trimethylphenyl)methanimine
• 英文别名: N-(2,4,6-trimethylbenzylidene)-methylamine
• CAS: 53699-37-9
• 化学式: C₁₁H₁₅N
• 分子量: 161.247
• InChiKey: VSNWNCPMFUAEAO-KPKJPENVSA-N

物化性质

• 沸点：
  249.0±39.0 °C(Predicted)
• 密度：
  0.88±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.66
• 重原子数：
  12.0
• 可旋转键数：
  1.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  12.36
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  二氧化碳 、 N-methyl-1-(2,4,6-trimethylphenyl)methanimine 、 2-(三甲基硅)苯基三氟甲烷磺酸盐 在 potassium fluoride 、 18-冠醚-6 作用下， 以 四氢呋喃 为溶剂， 反应 15.0h， 以82%的产率得到1-methyl-2-(2,4,6-trimethylphenyl)-1,2-dihydro-(4H)-benzo[d]-3,1-oxazin-4-one
  参考文献：
  名称：

  CO₂ Incorporation Reaction Using Arynes:  Straightforward Access to Benzoxazinone

  摘要：

  A zwitterion, generated from an aryne and an imine, has been demonstrated to serve as an excellent molecular scaffold for capturing CO2, which results in the straightforward formation of diverse benzoxazinones.

  DOI：

  10.1021/ja064157o

文献信息

• METAL-CATALYZED COPOLYMERIZATION OF IMINES AND CARBON MONOXIDE AS A ROUTE TO SYNTHESIZE POLYPEPTIDES
  申请人：SUN Huailin

  公开号：US20090264619A1

  公开（公告）日：2009-10-22

  Polypeptides of formula (I): wherein R 1 and R 2 are substituents independently selected from substituted and un-substituted alkyl groups and substituted and un-substituted aryl groups, and n is an integer greater than or equal to 2. Synthesis methods are also provided that do not use amino acids as starting materials, but instead employ imines and carbon monoxide as monomers that undergo transition metal-catalyzed alternating copolymerization to directly provide polypeptides using an acylcobalt catalyst with the following structural formula: wherein R is selected from the group consisting of alkyl, phenyl, and substituted phenyl groups.
• US8815913B2
  申请人：——

  公开号：US8815913B2

  公开（公告）日：2014-08-26