(5,10,15-tritolyl-isocorrolato)Co(triphenylphosphine) | 1392321-89-9

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: (5,10,15-tritolyl-isocorrolato)Co(triphenylphosphine)
• 英文别名: triphenylphosphine[5,10,15-tris-(4-methylphenyl)corrolato] cobalt(III)；(TTCor)Co(PPh3)
• CAS: 1392321-89-9
• 化学式: C₅₈H₄₄CoN₄P
• 分子量: 886.981
• InChiKey: MXICLOWCOHCVNZ-SATREPFYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (5,10,15-tritolyl-isocorrolato)Co(triphenylphosphine) 、 3-二甲氨基丙烯醛 在 三氯氧磷 作用下， 以 二氯甲烷 为溶剂， 以90 %的产率得到triphenylphosphine [3-(2-formylvinyl)-5,10,15-tritolylcorrolato]cobalt(III)
  参考文献：
  名称：

  Panchromatic and Perturbed Absorption Spectral Features and Multiredox Properties of Dicyanovinyl- and Dicyanobutadienyl-Appended Cobalt Corroles

  摘要：

  DOI：

  10.1021/acs.inorgchem.3c02666
• 作为产物：
  描述：

  5,10,15-tris(4-methylphenyl)corrole 、 cobalt(II) diacetate tetrahydrate 、 三苯基膦 在 sodium acetate 作用下， 以 四氢呋喃 为溶剂， 反应 1.58h， 以66%的产率得到(5,10,15-tritolyl-isocorrolato)Co(triphenylphosphine)
  参考文献：
  名称：

  钴和铑的Corrole-Triphenylphosphine配合物再访：非无害的Corrole的问题

  摘要：

  对钴-Corrole-三苯基膦配合物的重新研究产生了其电子结构的出乎意料的微妙图像。紫外可见吸收光谱，在X射线结构中观察到的骨架键长变化以及对称对称DFT（B3LYP）计算表明这些配合物具有部分Co II –腐蚀•2-特征。同样的探针应用于类似的铑腐蚀剂，没有证据表明它们是无害的腐蚀剂。X射线吸收光谱研究表明，相对于真正的Co（III）配合物Co [TPC]（），Co [TPC]（PPh 3）（TPC =三苯基甲氧基）的Co K上升沿红移了约1.8 eV。py）2和Co [TPP]（py）Cl（TPP =四苯基卟啉，py =吡啶），与Co [TPC]（PPh 3）的部分Co II –甲酸酯•2–描述一致。电化学测量表明，Co和Rh络合物均经历了两个可逆的氧化反应和一到两个不可逆的还原反应。尤其是，Rh杂化物的第一次还原发生的负电势比Co杂化物的负电明显多，这反映了相对于Co（III）而言，

  DOI：

  10.1021/acs.inorgchem.7b01828

文献信息

• β-Acrolein-Substituted Corroles: A Route to the Preparation of Functionalized Polyacrolein Microspheres for Chemical Sensor Applications
  作者：Andrea Savoldelli、Gabriele Magna、Corrado Di Natale、Alexandro Catini、Sara Nardis、Frank R. Fronczek、Kevin M. Smith、Roberto Paolesse

  DOI：10.1002/chem.201702380

  日期：2017.10.20

  An efficient β‐functionalization of [5,10,15‐tris‐(4‐methylphenyl)corrolato]cobalt derivatives through a Vilsmeier‐type reaction allows the introduction of an acrolein substituent, which is subsequently copolymerized with pure acrolein. The obtained hybrid microspheres are exploited as nanogravimetric chemical sensors. The sensing properties of the developed sensors are tested through exposure to different

  通过Vilsmeier型反应对[5,10,15-三（4-甲基苯基）-corrolato]钴衍生物进行有效的β官能化可以引入丙烯醛取代基，然后将其与纯丙烯醛共聚。所获得的杂化微球被用作纳米重力化学传感器。通过暴露在不同的挥发性有机化合物中作为模型分析物，测试了开发的传感器的传感特性。结果表明，相对于用Corrole或polyacrolein功能化的传感器，所得设备对所有测试分析物的传感器灵敏度都有所提高。增强的属性归因于两种开发材料的属性的精确和可调谐合并。
• Synthesis and Characterization of Free-Base, Copper, and Nickel Isocorroles
  作者：Giuseppe Pomarico、Xiao Xiao、Sara Nardis、Roberto Paolesse、Frank R. Fronczek、Kevin M. Smith、Yuanyuan Fang、Zhongping Ou、Karl M. Kadish

  DOI：10.1021/ic100730j

  日期：2010.6.21

  A series of free-base and metalated isocorroles represented as (TT-n-iso-Cor)H-2 and (TT-n-iso-Cor)M-II, where n=5 or 10 and M = Ni or Cu, were synthesized and characterized by electrochemistry and spectroelectrochemistry in CH2Cl2 containing 0.1 M tetra-n-butylammonium perchlorate. The metalation of the free-base macrocydes with Co-II, Mn-IIII, or Zn-II was also attempted but was unsuccessful. Six isocorroles were isolated and shown to undergo two stepwise oxidations to give pi-cation radicals and dications in CH2Cl2, with the most stable products being obtained in the case of the 10-substituted derivatives. The same isocorroles could also be reduced by one or two electrons, but the initial one-electron addition products are unstable and undergo a rapid chemical reaction giving a reduced corrole or corrole-like product, which could be reoxidized to the corresponding (TTCor)M at a controlled positive potential. This series of reactions effectively illustrates an isocorrole to corrole conversion upon reduction and reoxidation and was monitored by both electrochemistry and thin-layer spectroelectrochemistry.