[silver(I)(imidazole-4,5-dicarboxylic acid-1H)(triphenylphosphine)2] | 887423-66-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [silver(I)(imidazole-4,5-dicarboxylic acid-1H)(triphenylphosphine)2]
• 英文别名: [Ag(Himdc)(PPh3)2]
• CAS: 887423-66-7
• 化学式: C₄₁H₃₃AgN₂O₄P₂
• 分子量: 787.54
• InChiKey: GKMLTKDHVCWLTJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [silver(I)2(imidazole-4,5-dicarboxylate)(triphenylphosphine)2]2 、 三苯基膦 以0%的产率得到[silver(I)(imidazole-4,5-dicarboxylic acid-1H)(triphenylphosphine)2]
  参考文献：
  名称：

  Synthesis and molecular structures of a novel tetranuclear silver(I) cluster [Ag2(Himdc)(PPh3)2]2 (H3imdc = imidazole-4,5-dicarboxylic acid) and a mononuclear silver(I) complex [Ag(H2imdc)(PPh3)2]

  摘要：

  A novel tetranuclear silver(I) cluster, [Ag-2(Himdc)(PPh3)(2)](2) 1 (H(3)imdc = imidazole-4,5-dicarboxylic acid; O<^>N) was obtained by a reaction of the Ag-O bonding precursor [Ag(R-Hpyrrld)](2) (H(2)pyrrld = 2-pyrrolidone-5-carboxylic acid), PPh3 and H(3)mide. The mononuclear complex, [Ag(H(2)imdc)(PPh3)(2)](2), was also formed by the reactions using increased amounts of PPh3.In the solid state, complex I was a "bivalve"-like Ag-4 cluster, while complex 2 showed a supramolecular arrangement of the 4-coordinate AgP2(N<^>O) unit via the intermolecular hydrogen bonding interaction. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2005.09.012