5-methyl-2,4'-dinitro-1,1'-biphenyl | 70690-02-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-methyl-2,4'-dinitro-1,1'-biphenyl
• 英文别名: 2,4'-Dinitro-5-methylbiphenyl；3-Methyl-6,4'dinitro-biphenyl；4-Methyl-1-nitro-2-(4-nitrophenyl)benzene
• CAS: 70690-02-7
• 化学式: C₁₃H₁₀N₂O₄
• 分子量: 258.233
• InChiKey: NURMIUIHVDKUAK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  19
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  91.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  4-硝基甲苯 、 4-硝基苯胺 在 亚硝酸正戊酯 作用下， 生成 5-methyl-2,4'-dinitro-1,1'-biphenyl
  参考文献：
  名称：

  Eustathopoulos,H. et al., Bulletin de la Societe Chimique de France, 1979, vol. , p. 191 - 195

  摘要：

  DOI：

文献信息

• Diels-Alder Reaction of β-Fluoro-β-nitrostyrenes. Synthesis of Mono-fluorinated Six-Membered Derivatives
  作者：Roman V. Larkovich、Savva A. Ponomarev、Alexander S. Aldoshin、Andrey A. Tabolin、Sema L. Ioffe、Valentine G. Nenajdenko

  DOI：10.1002/ejoc.202000054

  日期：2020.5.10

  TOC Text: The Diels‐Alder reaction of β‐fluoro‐β nitrostyrenes with some linear dienes is reported. The kinetic studies were carried out to reveal substituent effect and activation parameters of the reaction. A new family of monofluorinated cyclohexenes 2 was prepared. The further transformation of 2 into biphenyls 3 based on base‐induced elimination of HNO2 followed by oxidative aromatization were

  TOC文本：报告了β-氟-β硝基苯乙烯与某些线性二烯的Diels-Alder反应。进行动力学研究以揭示取代基效应和反应的活化参数。制备了一个新的单氟环己酮家族2。描述了基于碱诱导的HNO 2消除和氧化芳构化作用，将2进一步转化为联苯3。
• Process for forming organic films on electrically conductive or semi-conductive surfaces using aqueous solutions
  申请人：Deniau Guy

  公开号：US20070289872A1

  公开（公告）日：2007-12-20

  The present invention concerns the area of surface coatings, the said coatings being in the form of organic films. It most especially relates to a method for forming copolymer organic films by electrochemical grafting on electrically conductive or semi-conductive surfaces using electrolytic aqueous solutions containing at least one protic solvent, at least one radically polymerizable monomer and at least one surfactant. The invention also concerns that surfaces obtained with the use of this method, their applications especially for preparation of microelectronic components, biomedical devices or screening kits, as well as the electrolyte solution used in the course of the method.
• US8152986B2
  申请人：——

  公开号：US8152986B2

  公开（公告）日：2012-04-10