1,3-Butadiene, 1,2-dichloro- | 3574-40-1

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: 1,3-Butadiene, 1,2-dichloro-
• 英文别名: (1Z)-1,2-dichlorobuta-1,3-diene
• CAS: 3574-40-1
• 化学式: C₄H₄Cl₂
• 分子量: 122.98
• InChiKey: CRNSOGJNJXTEQG-ARJAWSKDSA-N

物化性质

• 沸点：
  99.04°C (estimate)
• 密度：
  1.1803

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  6
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,3-Butadiene, 1,2-dichloro- 、 盐酸 以25%的产率得到
  参考文献：
  名称：

  TATEVOSYAN N. TS.; KAPLANYAN EH. E.; MKRYAN G. G.; KARAPETYAN G. M.; MKRY+, ARM. XIM. ZH., 39,(1986) N 10, 652-654

  摘要：

  DOI：
• 作为产物：
  描述：

  cis-1,2,4-trichloro-2-butene 、 sodium hydroxide 生成 1,3-Butadiene, 1,2-dichloro-
  参考文献：
  名称：

  KALAJDZHYAN A. E.; ROSTOMYAN I. M.; KURGINYAN K. A.; CHUXADZHYAN G. A., AJKAKAN KIMIAKAN AMSAGIR, ARM. XIM. ZH., 1980, 33, HO 1, 57-62

  摘要：

  DOI：

文献信息

• Method of continuously dissolving rubber
  申请人：TOYO ENGINEERING CORPORATION

  公开号：EP0870787A1

  公开（公告）日：1998-10-14

  A method of dissolving a rubber continuously to form a raw material for the production of rubber-modified polymer, by dissolving a rubber in a monomer liquid dissolving the rubber and capable of reacting with the rubber in the presence or absence of a solvent. Pieces of rubber are fed continuously to a dissolution tank to allow the dissolved rubber and the undissolved rubber to coexist in the dissolution tank, wherein the concentration of the dissolved rubber is the concentration at which the feeding to the reactor is made, and the quantity of the undissolved rubber present in the dissolution tank is at most the quantity that prevents pieces of the undissolved rubber from sticking to one another to form larger rubber masses. The time required for dissolution can be shortened, and the size of a dissolution tank can be made smaller, compared with the conventional methods.

  一种连续溶解橡胶以形成用于生产橡胶改性聚合物的原材料的方法，其方法是将橡胶溶解在溶解橡胶并能在有或无溶剂的情况下与橡胶发生反应的单体液体中。将橡胶块连续送入溶解槽，使溶解的橡胶和未溶解的橡胶在溶解槽中共存，其中溶解橡胶的浓度为向反应器进料时的浓度，而溶解槽中未溶解橡胶的数量最多为防止未溶解橡胶块相互粘连形成较大橡胶块的数量。与传统方法相比，溶解所需的时间可以缩短，溶解槽的尺寸也可以缩小。
• RESIN AND SURFACE PROTECTION PLATE OR AUTOMOTIVE MATERIAL
  申请人：Sumitomo Chemical Company, Ltd.

  公开号：EP3327052A1

  公开（公告）日：2018-05-30

  Provided is a resin including both a structural unit derived from a monomer having a carbon-carbon double bond at a terminal thereof and a structural unit derived from a polyrotaxane compound, wherein the polyrotaxane compound is a compound substituted with a (meth)acryloyl group or a group containing a (meth)acryloyl group, the polyrotaxane includes optionally substituted cyclodextrin, a linear molecule clathrated in the optionally substituted cyclodextrin in a skewer shape, and a capping group for preventing the optionally substituted cyclodextrin from leaving, the capping group being located at a terminal of the linear molecule clathrated in the optionally substituted cyclodextrin in a skewer shape, and the weight average molecular weight of the linear molecule clathrated in the optionally substituted cyclodextrin in a skewer shape is greater than or equal to 21000 and less than or equal to 500000.

  本发明提供了一种树脂，该树脂包括衍生自末端具有碳碳双键的单体的结构单元和衍生自聚二十六烷化合物的结构单元，其中聚二十六烷化合物是被(甲基)丙烯酰基或含有(甲基)丙烯酰基的基团取代的化合物，聚二十六烷包括任选取代的环糊精、呈串状凝集在任选取代的环糊精中的线性分子以及用于防止任选取代的环糊精离开的封端基团，封端基团位于呈串状凝集在任选取代的环糊精中的线性分子的末端、和用于防止任选取代的环糊精离开的封端基团，封端基团位于呈串状包覆在任选取代的环糊精中的线性分子的末端，且呈串状包覆在任选取代的环糊精中的线性分子的重量平均分子量大于或等于 21000，小于或等于 500000。
• ACRYLIC COPOLYMER, AND CROSSLINKED PRODUCT THEREOF
  申请人：Osaka Soda Co., Ltd.

  公开号：EP3549962A1

  公开（公告）日：2019-10-09

  The present invention provides an acrylic copolymer comprising structural units derived from an acrylic acid ester having an alkyl group and/or structural units derived from an acrylic acid ester having an alkoxyalkyl group; structural units derived from an alkyl methacrylate having 3 to 16 carbon atoms; and structural units derived from a cross-linkable monomer having a carboxy group. The present invention provides also a composition comprising the acrylic copolymer and a cross-linking agent, and a cross-linked product produced by cross-linking the composition. The acrylic copolymer, composition, and cross-linked product are suitable for a rubber material that has a low change rate of elongation and a small change in hardness and is excellent in heat resistance even if exposed to high temperature conditions for a long period of time.

  本发明提供了一种丙烯酸共聚物，该共聚物包含由具有烷基的丙烯酸酯衍生的结构单元和/或由具有烷氧基烷基的丙烯酸酯衍生的结构单元；由具有 3 至 16 个碳原子的甲基丙烯酸烷基酯衍生的结构单元；以及由具有羧基的可交联单体衍生的结构单元。本发明还提供了一种包含丙烯酸共聚物和交联剂的组合物，以及通过交联该组合物产生的交联产品。这种丙烯酸共聚物、组合物和交联产品适用于橡胶材料，即使长期暴露在高温条件下，其伸长率变化小，硬度变化小，耐热性能优异。
• ACRYLIC COPOLYMER AND RUBBER MATERIAL
  申请人：Osaka Soda Co., Ltd.

  公开号：EP3835331A1

  公开（公告）日：2021-06-16

  It is an object of the present invention to provide an acrylic copolymer for providing a highly heat-resistant rubber material that shows a small rate of change in strength without loss of elongation, even under a high-temperature condition over a long period, and a composition containing the acrylic copolymer. The present invention provides an acrylic copolymer comprising a structural unit (A) derived from a monomer containing a structure having a maleimide skeleton, a structural unit (B) derived from an acrylic acid alkyl ester and/or a structural unit (B) derived from an acrylic acid alkoxyalkyl ester, and a structural unit (C) derived from an unsaturated monomer having a crosslinking group; a composition comprising the acrylic copolymer and a crosslinking group; and a rubber material produced from the composition.

  本发明的目的是提供一种丙烯酸共聚物，用于提供一种即使在长期高温条件下强度变化率小而伸长率无损失的高耐热橡胶材料，以及一种含有该丙烯酸共聚物的组合物。本发明提供了一种丙烯酸共聚物，该共聚物包含由含有马来酰亚胺骨架结构的单体衍生的结构单元（A）、由丙烯酸烷基酯衍生的结构单元（B）和/或由丙烯酸烷氧基烷基酯衍生的结构单元（B）以及由具有交联基团的不饱和单体衍生的结构单元（C）；包含该丙烯酸共聚物和交联基团的组合物；以及由该组合物生产的橡胶材料。
• WAVELENGTH CONVERSION FILM, WAVELENGTH CONVERSION FILM FORMING COMPOSITION, AND CLUSTER-CONTAINING QUANTUM DOT PRODUCTION METHOD
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：EP3998324A1

  公开（公告）日：2022-05-18

  The objective of the invention is to provide a wavelength conversion film demonstrating a high optical density, a wavelength conversion film forming composition used suitably for forming the wavelength conversion film, and a production method for a cluster-containing quantum dot that may be applied suitably to the wavelength conversion film and the wavelength conversion film forming composition. In this invention, for a wavelength conversion film containing a quantum dot converting blue light into red light or green light, the light beam transmittance of the wavelength conversion film at 450 nm wavelength is set to 40% or lower, the light beam transmittance of the wavelength conversion film at 650 nm wavelength is set to 90% or higher if the hue of the light beam after the wavelength conversion is red, and the light beam transmittance of the wavelength conversion film at 550 nm wavelength is set to 90% or higher if the hue of the light beam after the wavelength conversion is green.

  本发明的目的是提供一种具有高光密度的波长转换膜、一种适合用于形成该波长转换膜的波长转换膜形成组合物，以及一种可适合应用于该波长转换膜和波长转换膜形成组合物的含团簇量子点的生产方法。在本发明中，对于含有将蓝光转换成红光或绿光的量子点的波长转换薄膜，波长为 450 nm 的波长转换薄膜的光束透过率设定为 40% 或更低、如果波长转换后的光束色调为红色，则波长 650 nm 处的波长转换薄膜的光束透射率设定为 90% 或更高，如果波长转换后的光束色调为绿色，则波长 550 nm 处的波长转换薄膜的光束透射率设定为 90% 或更高。