| 98499-19-5

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• CAS: 98499-19-5
• 化学式: C₁₆H₃₆N₅O₂Zn*ClO₄
• 分子量: 495.335
• InChiKey: XOBCXSUQBJYECL-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  硝基乙烷 、 [Zn(1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane)](ClO4)2 在 triethylamine 作用下， 以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  SYNTHESES, CHARACTERIZATION, AND MOLECULAR STRUCTURES OF NITROALKANOATO NICKEL(II), ZINC(II), AND CADMIUM(II) COMPLEXES WITH TETRAAZACYCLOALKANES

  摘要：

  Nickel(II), zinc(II), and cadmium(II) complexes of tetraazacycloalkane (L) (L = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane (L1), 7RS,14RS-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (L2), or 1,4,8,12-tetraazacyclopentadecane (L3)) react with nitroalkanes (RR’CHNO2 : R = R′ = H; R = H, R′ = CH3; R = R′ = CH3) in the presence of NEt3 to afford the nitroalkanoato complexes, [M(L)(O2NCRR’)]+ which have been characterized by IR, 1H and 13C NMR spectroscopy, and by X-ray analyses on three compounds.

  DOI：

  10.1246/cl.1985.1251