trans,cis,cis-[Pt(IV)(OOCCH3)(OCH3)(9-fluorenylidenemalonate)(2,2-dimethyl-1,3-propanediamine)]*N,N-dimethylformamide | 385825-17-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trans,cis,cis-[Pt(IV)(OOCCH3)(OCH3)(9-fluorenylidenemalonate)(2,2-dimethyl-1,3-propanediamine)]*N,N-dimethylformamide
• CAS: 385825-17-2
• 化学式: C₃H₇NO*C₂₄H₂₈N₂O₇Pt
• 分子量: 724.67
• InChiKey: VLQAWSQXJKHZGZ-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  2,2-dimethyl-1,3-propanediamine(9-fluorenylidenepropanedioato)hydroxomethoxoplatinum(IV)*2(methanol) 、 乙酸酐 、 N,N-二甲基甲酰胺 以 乙酸酐 为溶剂， 以80.3%的产率得到trans,cis,cis-[Pt(IV)(OOCCH3)(OCH3)(9-fluorenylidenemalonate)(2,2-dimethyl-1,3-propanediamine)]*N,N-dimethylformamide
  参考文献：
  名称：

  Unusual Fluorenylidene-philic Interactions for Effective Conformational Induction

  摘要：

  Control of the conformation of the fluorenylidene moiety is achieved through an intramolecular interaction between the fluorenylidene moiety and the axial ligand during the oxidative addition and successive substitution of [PtII (fm)] to give [PtIV (X)(X')(fm)] (fm=9-fluorenylidenemalonate; see scheme). The conformation of the fm moiety can be effectively induced by the fluorenylidene-philicity of the axial X/X' ligands, OOCCH3 >OCH3 >OH.

  DOI：

  10.1002/1521-3773(20011015)40:20<3868::aid-anie3868>3.0.co;2-o